A fine-particle transmission electron microscope investigation of CrO<sub>2</sub>and CrO(OH)

Krakow, William; Colijn, Hendrik O.; Müller, Olaf

doi:10.1080/01418618008239318

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Curve Fitting and Analysis1

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Cited by 5 publications

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“…Trivalent contaminants are a probable result of the reaction of trace water in the vacuum system with the dioxide. This leads to the formation of CrOOH, as has been shown by Krakow et al (21). The Cr2p~/~ binding energy of CrOOH is approximately the same as that of Cr(OH)~.…”

Section: Curve Fitting and Analysismentioning

confidence: 66%

Photoreduction of Hexavalent Chromium during X‐Ray Photoelectron Spectroscopy Analysis of Electrochemical and Thermal Films

Halada

Clayton

1991

J. Electrochem. Soc.

118

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Cr spectra obtained by x-ray photoelectron spectroscopy (XPS) of corrosion product layers is critically examined for evidence of photoreduction of hexavalent species. Tetravatent and trivalent decomposition products are identified, and methods of curve fitting and analysis are discussed. Disagreement between x~ray absorption near end structure and XPS data, and between thermodynamic analysis and XPS data lead to the acceptance of a model for photoreduction of Cr 6+ based primarily upon core photoemission.

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Section: Curve Fitting and Analysismentioning

confidence: 66%

Photoreduction of Hexavalent Chromium during X‐Ray Photoelectron Spectroscopy Analysis of Electrochemical and Thermal Films

Halada

Clayton

1991

J. Electrochem. Soc.

118

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show abstract

Advanced Ceramics and Nanocomposites of Half-metallic Ferromagnetic CrO2 for Magnetic, GMR and Optical Sensors

Ram

Biswas

J-Fecht

2008

Functional Nanostructures

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Kinetics and mechanistic aspcts of the interconversion process CrO2 ⇌' CrOOH. Isotopic effect

1985

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A fine-particle transmission electron microscope investigation of CrO₂and CrO(OH)

Cited by 5 publications

References 12 publications

Photoreduction of Hexavalent Chromium during X‐Ray Photoelectron Spectroscopy Analysis of Electrochemical and Thermal Films

Photoreduction of Hexavalent Chromium during X‐Ray Photoelectron Spectroscopy Analysis of Electrochemical and Thermal Films

Advanced Ceramics and Nanocomposites of Half-metallic Ferromagnetic CrO2 for Magnetic, GMR and Optical Sensors

Kinetics and mechanistic aspcts of the interconversion process CrO2 ⇌' CrOOH. Isotopic effect

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A fine-particle transmission electron microscope investigation of CrO2and CrO(OH)

Cited by 5 publications

References 12 publications

Photoreduction of Hexavalent Chromium during X‐Ray Photoelectron Spectroscopy Analysis of Electrochemical and Thermal Films

Photoreduction of Hexavalent Chromium during X‐Ray Photoelectron Spectroscopy Analysis of Electrochemical and Thermal Films

Advanced Ceramics and Nanocomposites of Half-metallic Ferromagnetic CrO2 for Magnetic, GMR and Optical Sensors

Kinetics and mechanistic aspcts of the interconversion process CrO2 ⇌' CrOOH. Isotopic effect

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Product

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About

A fine-particle transmission electron microscope investigation of CrO₂and CrO(OH)