Wearables is a category of electronic devices that can be worn as accessories, embedded in clothing, implanted in the user's body, or even tattooed on the skin. The past decade has witnessed rapid development of wearables in medicine, healthcare, military, and other fields. As predicted by global technology research firm CCS Insight, the market of wearables will reach almost $30 billion and the sales will reach 260 million units in 2023. [1] The rapid development of wearables is originated from the great successes achieved in materials, electronics, and other related techniques. Inversely, it also proposes more requirements to them. One typical example is the battery for the wearables. The appearance of portable chemical battery, especially the ultrathin large capacity lithium battery, makes the service of wearables possible. Inversely, the rapid development of wearables requires the batteries have better flexibility, smaller volume, larger capacity, and longer lifetime. [2] Among them, the longer lifetime of battery is one of the most important issues because the frequently charging process greatly limits the long-term service of wearables, which is particularly critical for the applications in medicine and military fields.Beyond the traditional chemistry battery, self-powered technology is attracting increasing attention in both academic and industry fields because it can provide uninterruptable power supply to wearables. [3] The most promising self-powered technology is thermoelectric technique, which can directly generate power by using the temperature difference between human body and environment based on the Seebeck effect. [4] It has the advantages of silent, reliable, and without moving parts. As early as 1960s, thermoelectric technique has been already used to power the deep space satellite to perform long-term exploration in deep space. Since the last decade of 20th century, due to the energy crisis and aggravated greenhouse gas emissions, the applications of thermoelectric technique were extended to the fields of waste heat harvesting. [5] In these applications, the heat sources usually have large area and thus the rigid thermoelectric materials and planar devices can satisfy the requirements. However, in wearables, the thermoelectric devices should be flexible to well fit the curved surface of human skin and survive under frequently bending process. This makes the development of flexible thermoelectric devices a very challenging task. Currently, flexible thermoelectrics, including flexible thermoelectric materials and devices, has already become a hot topic in thermoelectric community. The number of published academic studies included in Web of Science Database (WOS) relevant to the keywords "flexible thermoelectric material" and "flexible thermoelectric device" is continuously increasing, from 18 in 2010 to 205 in 2019.Flexible organic thermoelectric materials are natural candidates for flexible thermoelectric devices due to their intrinsic flexibility. [6] Likewise, via the help of flexible substrat...