A flotation combined extraction process for improving the whiteness of phosphogypsum

Abstract

Every year, the production of industrial phosphoric acid generates more than 100 Tg of phosphogypsum (PG), leading to significant environmental damage and the occupation of a vast amount of land space. The urgent need to explore applications for PG has become increasingly apparent. However, impurities such as organic substances, slime, phosphorite, and SiO2 reduce the whiteness of PG, making it difficult to utilize for high-value applications. To address this issue, this study employed a two-stage flotation process to remove the majority of impurities, including SiO2, organic substances, and fine slime adhered to the surface of PG particles. The raw PG sample was first sieved to remove some SiO2 particles. After flotation, sulfuric acid and tributyl phosphate were introduced to decompose the PG particles and remove the impurities wrapped inside. Following this flotation combined extraction process, the whiteness of the PG sample improved from 54.1% to 92.9%, meeting the requirements for building walls and filters.

Study on Mechanisms for Improving Quality and Whiteness of Phosphogypsum Based on Process Mineralogy Analysis

“…Therefore, the quality and whiteness of PG can be improved by employing mineral processing methods. Currently, investigators have conducted research on PG purification through flotation and coupling-flotation processes [13][14][15]. Qi et al [16] obtained gypsum concentrate with 69.2% whiteness and 97.24% purity through a reverse-positive flotation process.…”