The physical and dielectric properties of composites of known microwave materials, Zn 2 SiO 4 and Zn 3 B 2 O 6 , prepared by solid-state reaction, were investigated with the purpose of developing a low-loss dielectric material for low-temperature co-fired ceramic applications. An off-stoichiometric phase of Zn 2 SiO 4 with extra SiO 2 was used to avoid the occurrence of unreacted ZnO. During sintering, zinc borate was found to partially react with residual SiO 2 to form Zn 2 SiO 4 . The residual zinc borate was converted to a boron-rich glassy phase which helped to reduce the sintering temperature of the composite. Good relative sintering density (>90%) at temperatures below the melting temperature of zinc borate is indicative of a sintering mechanism of diffusion-based mass transfer. Composites containing 15 wt.% zinc borate, 2.5 wt.% lithium carbonate and 20 wt.% zinc borate in zinc silicate had dielectric constants of 6.8 and 6.1, quality factors (Q9f) of 48,800 and 94,300 GHz when sintered at 900°C and 950°C, respectively. These quality factor results are close to the best values reported for zinc silicate at these sintering temperatures.