“…The gases emitted by more than 90% of the mud volcanoes are thought to be derived mainly from hydrocarbon degradation, with maximum concentrations of CH 4 up to 99 vol.% (Caracausi et al, ; Chao et al, ; Etiope & Milkov, ; Huang et al, ; Wan et al, ). However, some mud volcanoes emit higher concentrations of CO 2 (12.0–84.7 vol.%) of biogenic, thermogenic, organic, or magmatic origin (Chao et al, ; Chaudhuri et al, ; Dimitrov, ; Kikvadze et al, ; Mazzini et al, ; Prinzhofer & Deville, ; Queißer et al, ; Wang & Chen, ).…”