Absorption, fluorescence and decay properties of erbium-doped alkali
tellurofluorophosphate glasses (RTFP) with the molar compositions of
50 (NaPO3)6–10 TeO2–20 AlF3–19 RF–1 Er2O3
(R = Li,Na
or K) have been investigated in order to utilize these materials for the development of fibre
amplifiers and lasers. The Judd–Ofelt (JO) model was applied to the absorption intensities of
Er3+
(4f11) transitions to determine the JO intensity parameters
Ωλ
(λ = 2,4
or 6). These evaluated intensity parameters are used to calculate the
spontaneous emission probabilities and branching ratios from the excited state
J manifolds to
the lower lying J′
manifolds of Er3+
emission transitions. The radiative lifetimes of these excited states are determined from their respective
spontaneous emission probabilities. Visible and NIR emission spectra have been studied for all three
Er3+-doped tellurofluorophosphate glasses. In particular, for the emission at
1.5 µm
corresponding to the transition, radiative parameters like the full width at half maximum (FWHM), emission cross-sections
(σe) and figure
of merit (FWHM ×
σe) were determined and compared with other hosts. The measured lifetimes of the
4S3/2
level are compared with predicted radiative lifetimes calculated from the JO theory. The potentiality
of Er3+-doped tellurofluorophosphate glasses for devices such as lasers and optical amplifiers is
discussed.