A High-Rate Lithium Manganese Oxide-Hydrogen Battery

Zhu, Zi‐Zhong; Wang, Mingming; Meng, Yahan; Lin, Zihan; Cui, Yi; Chen, Wei

doi:10.1021/acs.nanolett.0c00044

Cited by 41 publications

(29 citation statements)

References 34 publications

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“…We assembled the H 2 /H + battery in Swagelok cells in sealed hydrogen gas surroundings according to our previous reports. − In the measurements for full cells, the capacities and current rates are calculated based on the active mass of the CuHCF cathode material. Since the battery performance is largely dependent on the type and concentration of the electrolyte, we first explored the influence of sulfuric acid as the aqueous proton electrolyte.…”

Section: Results and Discussionsupporting

confidence: 91%

“…Hydrogen gas as an emerging anode delivers very low overpotentials, fast kinetics, and long-term stability in terms of reversible hydrogen evolution and oxidation reactions (HER/HOR) . In recent years, we proposed and demonstrated a class of rechargeable hydrogen gas batteries, which are empowered by the hydrogen gas anode that reacts by the proton charge carrier in aqueous solution, delivering a high rate and exceptional cycling performance. − For example, we recently presented a static iodine–hydrogen gas battery, which not only delivered a prominent performance with a high rate of 100 C and long cycle life of 60 000 cycles but also operated well in an acidic electrolyte . In addition, a novel manganese–hydrogen gas battery has attracted much attention in exploring acidic battery systems with fast reaction kinetics up to 100 C and long cycling stability over 10 000 cycles .…”

Section: Introductionmentioning

confidence: 99%

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An Ultrafast and Ultra-Low-Temperature Hydrogen Gas–Proton Battery

et al. 2021

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Aqueous proton batteries are regarded as one of the most promising energy technologies for next-generation grid storage due to the distinctive merits of H+ charge carriers with small ionic radius and light weight. Various materials have been explored for aqueous proton batteries; however, their full batteries show undesirable electrochemical performance with limited rate capability and cycling stability. Here we introduce a novel aqueous proton full battery that shows remarkable rate capability, cycling stability, and ultralow temperature performance, which is driven by a hydrogen gas anode and a Prussian blue analogue cathode in a concentrated phosphoric acid electrolyte. Its operation involves hydrogen evolution/oxidation redox reactions on the anode and H+ insertion/extraction reactions on the cathode, in parallel with the ideal transfer of only H+ between these two electrodes. The fabricated aqueous hydrogen gas–proton battery exhibits an unprecedented charge/discharge capability of up to 960 C with a superior power density of 36.5 kW kg–1, along with an ultralong cycle life of over 0.35 million cycles. Furthermore, this hydrogen gas–proton battery is able to work well at an ultralow temperature of −80 °C with 54% of its room-temperature capacity and under −60 °C with a stable cycle life of 1150 cycles. This work provides new opportunities to construct aqueous proton batteries with high performance in extreme conditions for large-scale energy storage.

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Section: Results and Discussionsupporting

confidence: 91%

Section: Introductionmentioning

confidence: 99%

An Ultrafast and Ultra-Low-Temperature Hydrogen Gas–Proton Battery

et al. 2021

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“…The cathode Mn 2+ /MnO 2 deposition/stripping reactions were initially demonstrated in the MnO 2 ‐H 2 battery by coupling it with a catalytic hydrogen gas anode as reported by Cui and coworkers. [ 76,142,143 ] The cathode reactions were conducted between soluble Mn 2+ and solid MnO 2 by reversible deposition/stripping, which is fundamentally different from the traditional solid‐state cathode reactions in the first generation Mn‐based batteries. The electrochemical reactions of the MnO 2 ‐H 2 battery can be described in the following:

\begin{matrix} \begin{matrix} left \\ Cathode : {Mn}^{2 +} + 2 {normalH}_{2} O \leftrightarrow {MnO}_{2} + 4 {normalH}^{+} + 2 {normale}^{-} \\ E_{0} = 1.228 V vs SHE \end{matrix} \end{matrix}

\begin{matrix} Anode : 2 {normalH}^{+} + 2 {normale}^{-} \leftrightarrow {normalH}_{2} E_{0} = 0 V vs SHE \end{matrix}

\begin{matrix} Overall : {Mn}^{2 +} + 2 {normalH}_{2} O \leftrightarrow {MnO}_{2} + 2 {normalH}^{+} + {normalH}_{2} E = 1.228 V \end{matrix}

…”

Section: Aqueous Mn‐based Batteries With Mn2+/mno2 Chemistrymentioning

confidence: 99%

Opportunities of Aqueous Manganese‐Based Batteries with Deposition and Stripping Chemistry

Wang

Zheng

Zhang

et al. 2020

Advanced Energy Materials

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141

108

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Rechargeable aqueous manganese‐based batteries have been attracting significant attention owing to their advantages of low cost, high safety, and ease of manufacturing, which are promising attributes for grid‐scale energy storage applications. However, most traditional manganese‐based batteries with solid‐state conversion and intercalation reactions suffer from low capacity and poor long‐term cycling stability. The recent novel storage mechanism based on cathode Mn2+/MnO2 deposition/stripping chemistry has fundamentally tackled these issues, enabling a new generation of manganese‐based batteries with superior electrochemical performance. Here, the recent advances in aqueous manganese‐based batteries with the Mn2+/MnO2 deposition/stripping chemistry are reviewed. A summary of the development of manganese‐based batteries with different storage mechanisms is provided and new opportunities for the emerging Mn2+/MnO2 chemistry in the latest generation are highlighted. Then, the current understanding of the Mn2+/MnO2 charge storage mechanism and its potential in manganese‐based batteries for large‐scale energy storage applications is presented. Moreover, insights into opportunities and future directions for manganese‐based batteries with the Mn2+/MnO2 chemistry are proposed.

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“…Consistent with our previous work [2][3][4][5][6][7] , the NCP-H2 battery was operated in a sealed condition as a pressurized cell. Before electrochemical tests, the assembled battery was purged with high-purity hydrogen (99.99%) to remove the air trapped in the battery.…”

Section: Fabrication Of the Swagelok Cellmentioning

confidence: 78%

Multifunctional NickelCobalt Phosphates for High-Performance Hydrogen Gas Batteries and Self-Powered Water Splitting

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A High-Rate Lithium Manganese Oxide-Hydrogen Battery

Cited by 41 publications

References 34 publications

An Ultrafast and Ultra-Low-Temperature Hydrogen Gas–Proton Battery

An Ultrafast and Ultra-Low-Temperature Hydrogen Gas–Proton Battery

Opportunities of Aqueous Manganese‐Based Batteries with Deposition and Stripping Chemistry

Multifunctional NickelCobalt Phosphates for High-Performance Hydrogen Gas Batteries and Self-Powered Water Splitting

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