In this paper, we give an integral representation for the boundary values of derivatives of functions of the de Branges-Rovnyak spaces H(b), where b is in the unit ball of H ∞ (C+). In particular, we generalize a result of Ahern-Clark obtained for functions of the model spaces K b , where b is an inner function. Using hypergeometric series, we obtain a nontrivial formula of combinatorics for sums of binomial coefficients. Then we apply this formula to show the norm convergence of reproducing kernel k b ω,n of the evaluation of n-th derivative of elements of H(b) at the point ω as it tends radially to a point of the real axis.