The study of the interaction between ionized jets, molecular outflows, and their environments is critical to understanding high-mass star formation, especially because jets and outflows are thought to be key in the transfer of angular momentum outward from accretion disks. We report a low spectral resolution Karl G. Jansky Very Large Array (VLA) survey for OH, NH3, CH3OH, and hydrogen radio recombination lines, toward a sample of 58 high-mass star-forming regions that contain numerous ionized jet candidates. The observations are from a survey designed to detect radio continuum; the novel aspect of this work is to search for spectral lines in broadband VLA data (we provide the script developed in this work to facilitate exploration of other data sets). We report detection of 25 GHz CH3OH transitions toward 10 sources; 5 of them also show NH3 emission. We found that most of the sources detected in CH3OH and NH3 have been classified as ionized jets or jet candidates and that the emission lines are coincident with, or very near (≲0.1 pc), these sources; hence, these molecular lines could be used as probes of the environment near the launching site of jets/outflows. No radio recombination lines were detected, but we found that the rms noise of stacked spectra decreases following the radiometer equation. Therefore, detecting radio recombination lines in a sample of brighter free–free continuum sources should be possible. This work demonstrates the potential of broadband VLA continuum observations as low resolution spectral-line scans.