A Highly Damping, Crack‐Insensitive and Self‐Healable Binder for Lithium‐Sulfur Battery by Tailoring the Viscoelastic Behavior

Abstract

Binder plays an important role in maintaining the integrity of sulfur electrode in lithium‐sulfur (Li‐S) battery. However, cracks are easily generated inside the electrode and compromise its performance due to the volume change of sulfur during redox reaction and continuous vibration originated from the external environments. It is a challenge yet crucial to develop tough binders with crack‐insensitivity and damping performance. Herein, a polymeric binder is designed with special viscoelastic behavior by tailoring its electrolyte‐philic and electrolyte‐phobic domains. The loss modulus of the binder is regulated to be highly close to its storage modulus within a wide range of frequency, generating an ultra‐high loss factor and equilibrium of viscosity‐elasticity. Based on such rheological behavior, the binder holds 1) high damping ability across a wide frequency to suppress crack generation, 2) high toughness with crack blunting behavior to resist crack propagation, 3) efficient healing capability to repair the cracks. Besides, the pendant zwitterionic groups can immobilize the lithium polysulfides and promote ion transfer. Benefiting from these advantages, the obtained Li‐S battery delivers high specific capacity with considerable capacity retention after long‐term cycling. The viscoelastic design and crack management strategy illustrated here would provide new insights into the binder design.

Multiresponsive Bilayer Hydrogel Actuator with Switchable Shape Morphing Capability and Visible Color/Fluorescence Change

“…Compared with the SEM image of the PADS gel (Figure S2), micelles with a size of 20–50 μm were observed within the PADS@DPM gel layer. The composition discrepancy was also confirmed by Fourier transform infrared spectroscopy (FTIR) (Figure b), where the PADS@DPM layer displayed characteristic peaks at 1108 cm –1 (stretching vibration of phenol groups) and 1400–1600 cm –1 (stretching vibration of the benzene ring), corresponding to the DP monomer. Conversely, these peaks were scarcely discernible in the transparent PND layer.…”

High Strength, Swelling Resistance, Antimicrobial and Conductive Zwitterionic Hydrogel Based on Cellulose Frame

“…Conductive hydrogels have excited enhancing interest due to the advantages of good electrical conductivity and ideal flexibility similar to that of human tissues, which demonstrating potential applications in tissue repair, , bone repair, , drug delivery, , electronic skin, soft robotics and wearable electronics. − However, conventional conductive hydrogels suffer from poor biocompatibility and low antimicrobial activity due to the addition of conductive fillers. Previous studies have confirmed that the introduction of zwitterionic segments into the hydrogel system could significantly improve its biocompatibility and antimicrobial activity by preventing the nonspecific adsorption of biomolecules such as cells, proteins and bacteria. − However, zwitterionic polymer based hydrogels are always weak because the strong ionic interaction nature of the polymers reduces the interactions between polymer chains.…”

Multifunction of MXene in Lithium–Sulfur Batteries: A Review

“…Many explorations have been carried out to relieve these problems. It mainly includes the structural design of the sulfur host material, the design of the separator structure, the optimization of the electrolyte and binder, and the advanced anode structure design strategies. − These strategies greatly improve the service life of the LSBs. Among various materials, carbon-based materials have the earliest and most extensive applications.…”