A highly fluorescent metal organic framework probe for 2,4,6-trinitrophenol detection via post-synthetic modification of UIO-66-NH2

Tang, Yilong; Wu, Huafeng; Chen, Jin‐Ming; Jia, Jinlan; Yu, Jinping; Xu, Wei; Fu, Yanyan; He, Qingguo; Cao, Huimin; Cheng, Jiangong

doi:10.1016/j.dyepig.2019.03.055

Cited by 52 publications

(22 citation statements)

References 34 publications

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“…As a next step, the azido–MOFs were converted into their isocyanate analogues by interaction with a CO flow at 423 K. The interaction was followed by in situ IR spectroscopy and nicely monitored through the gradual conversion of the ν as (N 3 – ) band at 2120 cm –1 to another band, at 2275 cm –1 , due to the ν as (NCO) mode . UiO-66–N 3 obtained by post synthesis modification of UiO-66–NH 2 , is characterized by a strong band at 2127–2124 cm –1 , due to the antisymmetric modes of the azide anion. , …”

Section: Vibrational Spectra Of Mofsmentioning

confidence: 99%

Power of Infrared and Raman Spectroscopies to Characterize Metal-Organic Frameworks and Investigate Their Interaction with Guest Molecules

et al. 2020

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The variety of functionalities and porous structures inherent to metal-organic frameworks (MOFs) together with the facile tunability of their properties makes these materials suitable for a wide range of existing and emerging applications. Many of these applications are based on processes involving interaction of MOFs with guest molecules. To optimize a certain process or successfully design a new one, a thorough knowledge is required about the physicochemical characteristics of materials and the mechanisms of their interaction with guest molecules. To obtain such important information, various complementary analytical techniques are applied, among which vibrational spectroscopy (IR and Raman) plays an important role and is indispensable in many cases. In this review, we critically examine the reported applications of IR and Raman spectroscopies as powerful tools for initial characterization of MOF materials and for studying processes of their interaction with various gases. Both the advantages and the limitations of the technique are considered, and the cases where IR or Raman spectroscopy is preferable are highlighted. Peculiarities of MOFs interaction with specific gases and some inconsistent band assignments are also emphasized. Summarizing the broad analytical possibilities of the IR and Raman spectroscopies, we conclude that it can be applied in combinations with other techniques to explicitly establish the structure, properties, and reactivity of MOFs.

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Section: Vibrational Spectra Of Mofsmentioning

confidence: 99%

Power of Infrared and Raman Spectroscopies to Characterize Metal-Organic Frameworks and Investigate Their Interaction with Guest Molecules

et al. 2020

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“…3H 2 O. DMF] n Cr 2 O 7 2− 0.058 µM 5 [419] [[Cu I 2 (ttpa) 2 ][Cu II (bptc)]. 3H 2 O. DMF] n CrO 4 2− 0.07 µM 5 [419] Cd-MOF S 2 O 8 2− – – [412] [Eu 2 L 3 (DMF)]·2 DMF PO 4 3− 6.62 µM – [420] c. Sensors for explosive compounds AuNCs/ZIF-8 TNT 5 nM – [413] [Tb(TCBA)(H 2 O) 2 ] 2 ·DMF TNP 1.64 ppb 5 [414] UIO-66-Py TNP 0.45 µM – [421] Eu-MOF TNP 0.03 mM – [422] Eu-MOF NB 0.04 mM – [422] Eu-MOF PNT 0.09 mM – [422] Eu-MOF PNP 0.08 mM – [422] HNU-34 TNP 36.15 nM 5 [415] HNU-34 2,4 DNP 42.55 nM 5 [415] ...…”

Section: Upcoming Mofs Applications For Future Commercializationmentioning

confidence: 99%

Recent advances in process engineering and upcoming applications of metal–organic frameworks

Ryu

Jee

Rao

et al. 2021

Coordination Chemistry Reviews

294

138

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“…UiO-66 is a MOF with Zr 6 O 4 (OH) 4 octahedral nodes that form lattices by 12-fold connection through 1,4-benzene-dicarboxylate (BDC) linkers (see Figures and ). UiO-66 has excellent chemical stability, mechanical stability, thermal stability, and water resistance, and it is widely used in the field of the host–guest chemistry for gas separation/adsorption, , fluorescence sensing, , catalysis, , water purification, and drug delivery. , UiO-66 forms a face-centered-cubic system that has 7.5 Å tetrahedral cages and 12 Å octahedral cages. , The zirconium ions in UiO-66 are not redox active, and this raises the question of how well alkali metals can be stored by interaction with the organic linkers. − …”

Section: Introductionmentioning

confidence: 99%

UiO-66 Metal–Organic Framework as an Anode for a Potassium-Ion Battery: Quantum Mechanical Analysis

Tang

Yin

et al. 2021

J. Phys. Chem. C

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The natural abundance of potassium in the earth's crust is 1000 times higher than that of lithium, so energy technologies built on potassium are more sustainable. Potassiumion batteries have attracted considerable attention because of their relatively low cost and high operating potential, but questions remain about the best anode material for such batteries. Here, we report first-principles computations based on density functional theory to investigate the performance of the UiO-66 metal− organic framework as an anode material for potassium-ion batteries; the goal is to provide a fundamental understanding of metal−organic framework (MOF)-based electrodes to guide the design and development of high-performance potassium-ion batteries. Our study includes the stability and electronic properties of potassiated structures and the mechanisms of potassium intercalation and diffusion in the framework. The results indicate that UiO-66 has a maximum specific capacity of 644 mAh/g as the anode of a potassium-ion battery. During potassiation, we observe charge transfer from potassium to carbon or oxygen of UiO-66 near the intercalated K. During K diffusion, the K migrates along the UiO-66 framework with a maximal migration energy barrier of 0.377 eV in the optimal pathway, which is much lower than the barriers for Li and Na diffusion in UiO-66. The diffusion coefficient of K in the anode is several orders of magnitude larger than those of Li and Na. This favors potassium ions over lithium ions or sodium ions when UiO-66 is the anode.

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A highly fluorescent metal organic framework probe for 2,4,6-trinitrophenol detection via post-synthetic modification of UIO-66-NH2

Cited by 52 publications

References 34 publications

Power of Infrared and Raman Spectroscopies to Characterize Metal-Organic Frameworks and Investigate Their Interaction with Guest Molecules

Power of Infrared and Raman Spectroscopies to Characterize Metal-Organic Frameworks and Investigate Their Interaction with Guest Molecules

Recent advances in process engineering and upcoming applications of metal–organic frameworks

UiO-66 Metal–Organic Framework as an Anode for a Potassium-Ion Battery: Quantum Mechanical Analysis

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