A Highly Selective and Sensitive Fluorescence Detection Method of Glyphosate Based on an Immune Reaction Strategy of Carbon Dot Labeled Antibody and Antigen Magnetic Beads

Wang, Duo; Lin, Bixia; Cao, Ya; Guo, Minzhe; Yu, Ying

doi:10.1021/acs.jafc.6b01088

Cited by 101 publications

(29 citation statements)

References 36 publications

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“…Capillary electrophoresis methods have been reported in recent years using detection systems such as contactless conductivity, electrochemiluminescence [100], and laser-induced fluorescence [101,102], as reviewed by Gauglitz et al [103]. Ion chromatography [104], electrochemical method, surface resonance-enhanced spectrometry, enzyme-linked immunosorbent assay also called ELISA methods [87], spectrophotometry [73,85], and fluorescent spectrometry [50,55,57,75,78,80,90,96] were also reported to detect GLY in current literatures. However, the selectivity of ion chromatography was limited.…”

Section: Other Methodsmentioning

confidence: 99%

Glyphosate Residues in Soil and Air: An Integrated Review

Tzanetou¹,

Karasali²

2020

Pests, Weeds and Diseases in Agricultural Crop and Animal Husbandry Production

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Glyphosate [N-(phosphonomethyl) glycine] (GPS) is currently the most commonly applied herbicide worldwide. Given the widespread use of glyphosate, the investigation of the relationship between glyphosate and soil ecosystem is critical and has great significance for its valid application and environmental safety evaluation. However, although the occurrence of glyphosate residues in surface and groundwater is rather well documented, only few information are available for soils and even fewer for air. Due to this, the importance of developing methods that are effective and fast to determine and quantify glyphosate and its major degradation product, aminomethylphosphonic acid (AMPA), is emphasized. Based on its structure, the determination of this pesticide using a simple analytical method remains a challenge, a fact known as the "glyphosate paradox." In this chapter a critical review of the existing literature and data comparison studies regarding the occurrence and the development of analytical methods for the determination of pesticide glyphosate in soil and air is performed.

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Section: Other Methodsmentioning

confidence: 99%

Glyphosate Residues in Soil and Air: An Integrated Review

Tzanetou¹,

Karasali²

2020

Pests, Weeds and Diseases in Agricultural Crop and Animal Husbandry Production

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“…In another example of solid-state pesticide detection, the detection of glyphosate in soil samples was accomplished using carbon dot-labeled labeled magnetic beads (Wang et al, 2016a). In this sensor, antibodies for glyphosate were attached to fluorescent carbon dots.…”

Section: Solid-state Pesticide Detectionmentioning

confidence: 99%

Fluorescence-Based Sensing of Pesticides Using Supramolecular Chemistry

Levine

2021

Front. Chem.

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The detection of pesticides in real-world environments is a high priority for a broad range of applications, including in areas of public health, environmental remediation, and agricultural sustainability. While many methods for pesticide detection currently exist, the use of supramolecular fluorescence-based methods has significant practical advantages. Herein, we will review the use of fluorescence-based pesticide detection methods, with a particular focus on supramolecular chemistry-based methods. Illustrative examples that show how such methods have achieved success in real-world environments are also included, as are areas highlighted for future research and development.

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“…Hence, the Glyp molecule must be derivatized, and this often involves lengthy chemical procedures. Besides chromatographic methods, analytical ap-proaches based on fluorescence [18] and electrophoresis [19] have also been employed for sensitive and selective detection of Glyp in river water and soil samples. Nevertheless, these methods are highly expensive, require lengthy analysis time, and depend on bulky instrumentation; thus, they are unsuitable for field monitoring.…”

Section: Introductionmentioning

confidence: 99%

An Electrochemically Synthesized Nanoporous Copper Microsensor for Highly Sensitive and Selective Determination of Glyphosate

et al. 2020

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A nanoporous copper (NPC) film was electrodeposited on a copper microelectrode, and the generated platform was investigated for electrochemical sensing of glyphosate (Glyp). The as-deposited NPC film was highly pure and crystalline according to results of energy dispersive spectroscopy and Xray diffraction experiments, respectively. Scanning electron microscopy images confirm the NPC films possess a highly porous morphology containing dendrite fractals, and the electrodeposition parameters, particularly potential (E d ) and time (t d ), exert a remarkable influence on the structure of the films. Such changes in the NPC morphology with E d and t d were also correlated with the electrochemical behavior investigated by cyclic voltammetry. In the presence of Glyp, the anodic oxidation is facilitated because copper ions diffuse easily through the pores of the NPC film and form a complex with the analyte at the electrode interface. On the other hand, as the amount of copper oxides decreases due to the formation of soluble Cu(II) complex with Glyp, less current is obtained during the reverse scan, allowing a relationship between the decrease in the cathodic current and the Glyp concentration to be established. The optimized NPC-modified Cu microelectrode showed very high sensitivity (14 nA nmol À 1 L), low detection limit (4 nmol L À 1 ), excellent reproducibility, and selective response for Glyp. The applicability of the sensor was demonstrated by detecting Glyp in river water samples.[a] Dr.

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A Highly Selective and Sensitive Fluorescence Detection Method of Glyphosate Based on an Immune Reaction Strategy of Carbon Dot Labeled Antibody and Antigen Magnetic Beads

Cited by 101 publications

References 36 publications

Glyphosate Residues in Soil and Air: An Integrated Review

Glyphosate Residues in Soil and Air: An Integrated Review

Fluorescence-Based Sensing of Pesticides Using Supramolecular Chemistry

An Electrochemically Synthesized Nanoporous Copper Microsensor for Highly Sensitive and Selective Determination of Glyphosate

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