Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) films incorporating 40 wt % of different types of imidazolium ionic liquids (ILs) comprising different magnetic anions (tetrachloroferrate [FeCl 4 ] − , tetrathiocyanatocobaltate [Co(SCN) 4 ] 2− , and tetrachlorocobaltate [CoCl 4 ] 2− ) and imidazolium cation chain lengths (1-butyl-3-methylimidazolium and 1ethyl-3-methylimidazolium) have been developed for humiditysensing applications. The influence of the different ILs on the morphology of the IL/PVDF-HFP composites has been evaluated, with a porous structure observed independently of the IL anion type and cation chain length. The inclusion of the ILs into PVDF-HFP induces polymer crystallization into the electroactive β phase, with the increase more noticeable for PVDF-HFP/[Bmim][FeCl 4 ], which reaches a β phase content of 85%. The degree of crystallinity slightly decreases with the incorporation of the filler and the incorporation of [Bmim] 2 [CoCl 4 ], [Bmim] 2 [Co(SCN) 4 ], and [Emim] 2 [Co(SCN) 4 ], leading to a degree of crystallinity between 11 and 13%. A decrease in the thermal stability and yield strength is observed in the hybrid samples with respect to neat PVDF-HFP, with this decrease being more noticeable for the PVDF-HFP/[Bmim] 2 [Co(SCN) 4 ] samples. Further, the highest magnetization has been obtained for the PVDF-HFP/[Bmim] 2 [Co-(SCN) 4 ] and PVDF-HFP/[Bmim][FeCl 4 ] composites with similar filler concentrations. The suitability of the developed materials for humidity sensing has been evaluated by analyzing the impedance variation with varying relative humidity from 30 to 85%. [Bmim] 2 [CoCl 4 ]/PVDF-HFP displays the highest relative humidity (RH) sensing response of −2245 ± 240 Ω/RH. Finally, the applicability of the developed hybrid IL/polymer composites has been demonstrated by the development of a real-time breathing monitoring device.