A kinetic study of propylene dimerization by binuclear nickel—ylide complexes in presence of diethylaluminium chloride as cocatalyst

Mitkova, Magdalena; Tomov, Atanas K.; Kurtev, K.

doi:10.1016/1381-1169(96)00025-8

Cited by 5 publications

(3 citation statements)

References 24 publications

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“…The complexes, which were generated from the appropriate bis(ylide), were assessed in ethylene oligomerisation and polymerisation 73, 74 as well as in propylene dimerisation. 75 The study revealed that the selectivity in linear olefins of the bimetallic catalysts 46-48, when used as oligomerisation catalysts, is much lower than that of comparable mononuclear systems (Table 8). Thus, beside the expected a-olefins, internal olefins as well as cooligomerisation products such as 2-ethyl-1-butene are formed.…”

Section: Bimetallic Catalystsmentioning

confidence: 94%

Structure–reactivity relationships in SHOP-type complexes: tunable catalysts for the oligomerisation and polymerisation of ethylene

et al. 2007

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For over 30 years complexes with the general formula [NiPh(P,O)L] (L = tertiary phosphine; P,O = chelating phosphanylenolato ligand) have been used as highly efficient oligomerisation catalysts suitable for the production of linear alpha-olefins. The same complexes, which are usually referred to as SHOP-type catalysts (SHOP = Shell Higher Olefin Process) can also be used as ethylene polymerisation catalysts, provided they are treated with a phosphine scavenger that selectively removes the tertiary phosphine ligand (L). This Perspective examines the impact of various parameters (influence of the substituents, backbone size, solvent, use of co-catalysts, etc.) on the catalytic outcome of the complexes. Overall, this review shows that the selectivity and activity of the catalyst may be tuned efficiently through directed modification of the P,O chelator.

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Section: Bimetallic Catalystsmentioning

confidence: 94%

Structure–reactivity relationships in SHOP-type complexes: tunable catalysts for the oligomerisation and polymerisation of ethylene

et al. 2007

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“…Catalysts 92a , e are highly active for propylene dimerization when activated by Et 2 AlCl. Kinetic studies using 92e indicate that the reaction rate is first and second order with respect to the concentration of the catalyst and propylene, respectively …”

Section: Binuclear Neutral Nickel Catalystsmentioning

confidence: 99%

Neutral Nickel Catalysts for Olefin Homo- and Copolymerization: Relationships between Catalyst Structures and Catalytic Properties

et al. 2015

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“…There are different pathways for the dimerization of alpha olefins and this reaction is generally non regioselective [12][13][14] (see Scheme 1). Most of the catalysts generate vinylidene dimers (2-alkyl-1-alkene) or dibranched dimers and are not selective for linear dimers.…”

Section: The Dimerization Of Light Olefinsmentioning

confidence: 99%

Oligomerization of Monoolefins by Homogeneous Catalysts

Forestière¹,

Olivier‐Bourbigou²,

Saussine³

2009

Oil & Gas Science and Technology - Rev. IFP

208

199

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Résumé -Oligomérisation des mono-oléfines par des catalyseurs homogènes -Cet article résume les différents schémas réactionnels pour l'oligomérisation des mono-oléfines par catalyse homogène, en particulier pour l'oligomérisation de l'éthylène et des alpha-oléfines. Les principaux sujets abordés sont la production régiosélective ou non de dimères, la production d'alpha-oléfines linéaires par oligomérisation de l'éthylène ainsi que la dimérisation sélective de l'éthylène et sa trimérisation sélective. Plusieurs procédés industriels développés par l'IFP sont présentés pour illustrer ce sujet. Abstract -Oligomerization of Monoolefins by Homogeneous Catalysts

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A kinetic study of propylene dimerization by binuclear nickel—ylide complexes in presence of diethylaluminium chloride as cocatalyst

Cited by 5 publications

References 24 publications

Structure–reactivity relationships in SHOP-type complexes: tunable catalysts for the oligomerisation and polymerisation of ethylene

Structure–reactivity relationships in SHOP-type complexes: tunable catalysts for the oligomerisation and polymerisation of ethylene

Neutral Nickel Catalysts for Olefin Homo- and Copolymerization: Relationships between Catalyst Structures and Catalytic Properties

Oligomerization of Monoolefins by Homogeneous Catalysts

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