A Lagrangian model with simple primary and secondary aerosol scheme 1: comparison with UK PM<sub>10</sub> data

Abstract

Abstract. A Lagrangian trajectory model used to simulate photochemistry has been extended to include a simple parameterisation of primary and secondary aerosol particles. The model uses emission inventories of primary particles for the UK from the NAEI (National Atmospheric Emissions Inventory for the UK), and for Europe from the TNO (Institute of Environmental Sciences, Energy Research and Process Innovation, the Netherlands) respectively, to transport tracers representing PM10. One biogenic and two anthropogenic organic compounds were chosen as surrogates to model the formation of condensable material suitable for the production of secondary organic aerosol (SOA). The SOA is added to the primary PM10 and compared to measured PM10 at one urban and two rural UK receptor sites. The results show an average under-prediction by factors of 4.5 and 8.9 in the urban and rural cases respectively. The model is also used to simulate production of two secondary inorganic species, H2SO4 and HNO3, which are assumed, as a limiting case, to be present in the particle phase. The relationships between modelled and measured total PM10 improved with the addition of secondary inorganic compounds, and the overall model under-prediction factors are reduced to 3.5 and 3.9 in the urban and rural cases respectively. Nevertheless, our conclusion is that current emissions and chemistry do not appear to provide sufficient information to model PM10 well (i.e. to within a factor of two). There is a need for further process studies to inform global climate modelling that includes climate forcing by aerosol.

Development and Application of an Urban Tree Air Quality Score for Photochemical Pollution Episodes Using the Birmingham, United Kingdom, Area as a Case Study

“…Model Description. The Cambridge tropospheric trajectory model of chemistry and transport (CiTTyCAT) is an air parcel model, described in detail by Evans et al (20) and Emmerson et al (21) and summarized here. It is developed from the work of Wild (22) and Wild et al (23).…”

Overview: oxidant and particle photochemical processes above a south-east Asian tropical rainforest (the OP3 project): introduction, rationale, location characteristics and tools

“…Thus, the CiTTyCAT model Evans et al, 2000;Emmerson et al, 2004;Donovan et al, 2005) has been used to study the chemical regimes probed by the OP3 measurements, both over the rainforest and over palm oil plantations, and to explore how local air quality could be affected should palm oil (a major isoprene-emitter) become an even more dominant crop, replacing the rainforest. Hewitt et al (2009) show that under these circumstances, what happens to local and regional-scale emissions of NO x will be crucial.…”

Simulating atmospheric composition over a South-East Asian tropical rainforest: performance of a chemistry box model

“…The CiTTyCAT atmospheric chemistry model Evans et al, 2000;Emmerson et al, 2004;Donovan et al, 2005) was run in stationary-box mode at ground level over the Bukit Atur GAW site. Unless otherwise stated, all model species are allowed to evolve freely and are not constrained to observations.…”