2018
DOI: 10.1002/aic.16451
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A lattice boltzmann approach to surfactant‐laden emulsions

Abstract: We present a pseudopotential lattice Boltzmann method to simulate liquid–liquid emulsions with a slightly soluble surfactant. The model is investigated in 2‐D, over a wide parameter space for a single, stationary, immiscible droplet, and surface tension reduction by up to 15% is described in terms of a surfactant strength Λ (which roughly follows a Langmuir isotherm). The basic surfactant model is shown to be insufficient for arresting phase segregation—which is then achieved by changing the liquid–liquid inte… Show more

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Cited by 21 publications
(11 citation statements)
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“…On the other hand, in the mid-range interaction model, the resulting disjoining pressure can be evaluated and, hence, there might be a way to relate it to the experimental isotherms. Third, it is reported in the work from Mukherjee et al [24] that the model by itself could not inhibit the bubbles coalescence.…”
Section: Introductionmentioning
confidence: 92%
“…On the other hand, in the mid-range interaction model, the resulting disjoining pressure can be evaluated and, hence, there might be a way to relate it to the experimental isotherms. Third, it is reported in the work from Mukherjee et al [24] that the model by itself could not inhibit the bubbles coalescence.…”
Section: Introductionmentioning
confidence: 92%
“…Figure 9 duplicates a scaled image of density at the steady-state condition. As stated by Mukherjee et al, the exact location of droplet edge is uncertain 100 . Therefore, a subpixel edge location based on partial area effect that is an image processing technique is implemented to increase the accuracy of droplet radius determination 101 .…”
Section: Laplace Law Testmentioning
confidence: 99%
“…Swift et al introduced the Free Energy method 33,34 and He et al 35 finally proposed the so-called HCZ method (from He, Chen and Zhang who first proposed the method), which recently received a lot of attention since the work of Fakhari [36][37][38][39] Geier et al 40 and Mitchell 4127 . Having greatly benefited from the advances in the phase field community 42,43 , these methods were applied on a large range of cases: droplet impact 44 , free jet 45 , ternary fluid 46 , drop impact on a liquid film 47 , flow with surfactant 48 , direct-writing printing 49 and also widely in porous flow 50 . HCZ method allows to simulate a large range of flows at both large density ratios and large Reynolds numbers 41 , while other methods are limited to moderate density ratios and / or moderate Reynolds numbers.…”
Section: Introductionmentioning
confidence: 99%