Photoassisted energy storage is a promising approach
to realizing
the utilization of solar power, and the reasonable design of a photoassisted
supercapacitor with photosensitive materials is one of the efficient
ways to realize solar power conversion and storage. Herein, we design
a photoassisted supercapacitor electrode (TiO2/CF) by integrating
a photoelectrode (TiO2) and a capacitive electrode (CF)
together, which achieves photoelectric synergistic charge storage.
It is found that spherical TiO2 precursors will crash,
expand, integrate, stretch, and tear, forming a reticulated structure.
Reticulated TiO2 guarantees illumination, which can boost
the utilization of solar power. The TiO2/CF electrode exhibits
a considerable (1.9-fold) increase in capacitance performance under
light conditions as compared to dark conditions. Furthermore, this
TiO2/CF photoassisted supercapacitor electrode exhibits
an excellent cycle stability of about 99.19% after 5000 cycles. Moreover,
the enhancement mechanism is elaborated as follows: these high-energy
photoelectrons will participate in charge transfer to increase the
total energy of the process, thereby enhancing capacitance performance.
In addition, these photoelectron–hole pairs act as additional
charge carriers to favor charge accumulation. This work may offer
new prospects for developing photoassisted energy supply systems for
the utilization of solar power.