The Internet of Things (IoT) was a new concept that connected various physical things to the internet. The IoT is fast expanding and will soon significantly impact everyday life. Although the increasing number of connected IoT devices is simplifying life, they risk our data. Radiofrequency identification (RFID) assists in the automated identification of connected IoT devices. Furthermore, the primary challenges for RFID tag-connected technology are privacy and security. With the improving safety of solutions RFID for many apps, RFID necessitates a centralized database widening. Blockchain techniques are speedily establishing themselves together as a new distributed and decentralized replacement. And it provides enhanced transparency, data security, immutability, dependability, and lower maintenance costs. Because of its inherent benefits, RFID is projected to play a significant part in enabling identifying technology on the IoT. However, due to its association with sensor technology, it has the potential to be applied in a wide range of industries. Security, however, is one of the more complex components of creating an RFID system. RFID Security focuses around authentication and privacy concerns. From the previous works, we found that the computing cost and uptime are higher. To solve these problems, we offer improving lightweight authentication using Arnold Chaotic map and Markov chain for IoT applications. The proposed method uses random algorithms (Markova chain, Arnold map chaotic, and ECC), which add high security. We also used blockchain technology to transfer keys through a non-security channel. Based on parameters such as (communication cost, throughput rate, storage requirements, transmission delay, and computational cost) the results of the proposed RFID protocol were compared with several RFID-based security solutions. As a result, the proposed lightweight scheme is more efficient and secure than existing RFID systems in terms of performance, according to simulation results, and is fully compatible with actual applications.