2024
DOI: 10.1021/acs.cgd.3c01061
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A Linear Trinuclear Acetate Bridged Cobalt Complex Containing Pyridine-Based Bicompartmental Ligand: Synthesis, Structural, Magnetic, and Electrocatalytic Oxygen Evolution Studies

Ezhava Manu Manohar,
Soumalya Roy,
Sujoy Bandyopadhyay
et al.

Abstract: The reaction of Co(OAc) 2 •4H 2 O, LH 2 , and Et 3 N in a 1.5:1:3 molar ratio affords a linear trinuclear complex, [Co 3 (L) 2 (μ-η 1 : η 1 -OAc) 2 (CH 3 CN) 2 ] (1). The synthesized complex was characterized by single crystal X-ray diffraction studies, and it exhibited better electrocatalytic activity for the oxygen evolution reaction (OER) compared with the catalyst, RuO 2 . The complex exhibits an overpotential of 380 mV at 10 mA cm −2 current density for the OER, which is better than that of RuO 2 (480 mV)… Show more

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“…A modified version of a method that had been previously documented 64 was employed to synthesise the highly pure, yellow-coloured ligand, H 2 L. 65…”
Section: Methodsmentioning
confidence: 99%
“…A modified version of a method that had been previously documented 64 was employed to synthesise the highly pure, yellow-coloured ligand, H 2 L. 65…”
Section: Methodsmentioning
confidence: 99%