This research proposes a compact quadri-cluster broadband circularly polarized (CP) sequentially-rotated metasurface-based (MTS) antenna array for the C-band frequency spectrum. One cluster of the quadri-cluster MTS-based antenna array consisted of 4 × 4 S-shaped periodically-arranged MTS elements. The sequentially-rotated feed network was utilized to realize circular polarization and improve the impedance bandwidth (IBW), 3-dB axial ratio bandwidth (ARBW) and 3-dB boresight gain bandwidth of the quadri-cluster MTS-based antenna array. Simulations were performed and results were compared with experiments. The measured IBW and ARBW were 84.74% (4.0 -9.0 GHz) and 57.6% (4.2 -7.6 GHz) at the center frequency of 5.9 GHz, rendering the proposed quadri-cluster MTS-based antenna array suitable for satellite communication applications. In addition, the quadri-cluster MTS-based antenna array achieved the measured 3-dB boresight gain bandwidth of 81.3% (3.9 -8.7 GHz), the maximum gain of 10.04 dBic at 5.6 GHz, and low radar cross-section. Specifically, the novelty of this research lies in the use of the sequentially-rotated feed network with the S-shaped MTS elements to effectively enhance ARBW of the quadri-cluster MTS-based antenna array for the C-band frequency spectrum.