Org. Biomol. Chem.
 2024
DOI: 10.1039/d4ob00886c
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A macrocycle-based new organometallic nano-vessel towards sustainable C2-selective arylation of free indole in water

Subham Mandal,
Piyali Sarkar,
Pradyut Ghosh

Abstract: C2-selectivity of unsubstituted indole over facile C3-substitution is attempted by utilizing the π-cavity of a nano-vessel made up of a palladium complex of an amino-ether heteroditopic macrocycle.

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