A Macrokinetic Study of the High-Temperature Solid-Phase Titanium−Carbon Reaction

Kostogorova, J.; Viljoen, Hendrik J.; Shteĭnberg, A. S.

doi:10.1021/ie030337k

Cited by 7 publications

(2 citation statements)

References 13 publications

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“…The surface contact between the fibre and matrix plays an important role in the following diffusion and chemical reaction stages. It determines the rates of diffusion and chemical reactions (Kostogorova et al, 2002;Kostogorova and Viljoen, 2003;Richter and Viljoen, 2002). When the fibre and matrix come into contact at elevated temperatures employed in the HIP process, the atoms in both surfaces are excited, jumping out of the surface potential well and hop from the original sites to new sites across the interface.…”

Section: Scrutiny Ofmentioning

confidence: 99%

A study of interface reaction zone in a SiC fibre/Ti-17 composite

Fan

Zhou

2018

Micron

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The interface reaction zone (RZ) in a unidirectional continuous carbon-coated SiC fibre reinforced Ti-17 titanium alloy composite is investigated. Micro-computed tomography (CT), scanning and transmission electron microscopy are employed to characterize the fibre/matrix interface. It is revealed that the interface RZ is a 400 nm thick titanium carbide (TiC) layer which is composed of two sublayers, a 60 nm thick fine-grained sublayer and an approximate 340 nm thick coarse-grained sublayer. The RZ is formed through chemical reaction between carbon coating on the SiC fibre surface and Ti, Zr and Sn in the alloy matrix. The reaction is controlled by atom diffusion occurring at the fibre/matrix interface. However, in the reaction process, Al, Cr and Mo in the matrix are rejected and piled up in front of the RZ on the matrix side. A structure model is proposed to describe the formation mechanism of the interface RZ.

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Section: Scrutiny Ofmentioning

confidence: 99%

A study of interface reaction zone in a SiC fibre/Ti-17 composite

Fan

Zhou

2018

Micron

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“…These studies have provided valuable kinetic data in extremely high-temperature ranges that are essentially inaccessible by other Advanced Chemical Kinetics 170 methods. For carbides, the Ti/C system has been studied [13][14][15], with additional studies in the Ta/C [14,16] and Si/C [14,17] mixtures. The Ti/B system was also investigated [18].…”

Section: Electrothermal Explosionmentioning

confidence: 99%

Kinetics of Heterogeneous Self-Propagating High-Temperature Reactions

Shuck¹,

Mukasyan²

2018

Advanced Chemical Kinetics

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In this chapter, we present an overview of experimental techniques utilized and kinetic data collected for exothermic self-sustained noncatalytic heterogeneous reactions. The data focuses on five primary experimental techniques: electrothermal explosion, differential thermal analysis, electrothermography, combustion velocity/temperature analyses, and several advanced in situ diagnostics, including time-resolved X-ray diffraction.

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Thermal analysis of high-temperature fast reactions in energetic materials

Shteĭnberg¹

2011

J Therm Anal Calorim

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A Macrokinetic Study of the High-Temperature Solid-Phase Titanium−Carbon Reaction

Abstract: An experimental method, electro thermal explosion (ETE), is used to measure the macro kinetic parameters of the high-temperature titanium/carbon reaction. Different stages of the reaction

Cited by 7 publications

References 13 publications

A study of interface reaction zone in a SiC fibre/Ti-17 composite

A study of interface reaction zone in a SiC fibre/Ti-17 composite

Kinetics of Heterogeneous Self-Propagating High-Temperature Reactions

Thermal analysis of high-temperature fast reactions in energetic materials

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