Liquid carbon dioxide phase change fracturing technology (LCPCFT) has been widely used in engineering blasting due to the advantage of no flames, and no toxic and harmful gas. However, few studies have been conducted on the acquisition of shock wave pressure and its loading characteristics, which are key parameters in fracturing. Referring to the CO 2 in-situ fracturing technology, an indoor test system for shock wave pressure generated during LCPCFT has been built, with a protected polyvinylidene fluoride (PVDF) piezoelectric sensor. Then three verification experiments with different radial distances between the fracturing tube and test points were carried out on the test system, and in each experiment, four PVDF sensors as four test points were arranged with different axial distance from the detonating point to test the pressure distribution. The experimental results show that when the radial distance between the fracturing tube and test points is not too large (≤345 mm), the pressure generated during LCPCFT is approximately uniformly distributed within the axial length of the fracturing tube, but when it is relatively large (≈895 mm), the results between different test points are in a certain degree of dispersion. And finally, this paper uses the intraclass correlation coefficient (ICC) and coefficient of variation (C V ) of peak pressure and impulse to process the test results to evaluate the reliability and stability of the test system. Evaluation results show that the test results are in good consistency. The test system in this paper has good stability and high reliability. The test system provides a useful tool for accurately obtaining the shock wave pressure, which is helpful for further research on LCPCFT.Hu [6] conducted permeability enhancement experiments of a coal seam by using LCPCFT; the test results show that cracks generated inside the coal seam will greatly increase the gas permeability of the coal seam. In addition, the process of LCPCFT is endothermic, which belongs to cold blasting, so the process of permeability enhancement is safer and more environmentally friendly. Because the small surface tension of supercritical CO 2 , it can penetrate into the interior of rock mass along the cracks, therefore the rock failure is accompanied by the generation of tensile cracks [7], and its rock breaking ability is usually better than that of a water jet [8]. Under the effect of competitive adsorption, the gaseous CO 2 produced during the fracturing process will convert the gas absorbed in the coal seam to a free state, which will increase the amount of gas released and reduce the possibility of a gas outburst during excavation [9]. Through experiments and numerical simulations, Sun [10] believed that the rock breaking under LCPCFT is the result of a stress wave and gasified CO 2 ,and the influence of initial confining pressure and blasting pressure on the effect of LCPCFT are also analyzed [11]. Zhu [12] analyzed the damage evolution process of concrete specimens under the action of high-pressure gas e...