“…That is, they are subject to no external potential, apart from being confined in a box of volume L 3 = V with periodic boundary conditions. 28 The single-particle quantum eigenstates 28 That is, the value of ψ at the walls need not be zero (as for an infinite square well), but rather must agree on opposite sides, so ψ(0, y, z) ≡ ψ(L, y, z), ψ(x, 0, z) ≡ ψ(x, L, z), and ψ(x, y, 0) ≡ ψ(x, y, L). Periodic boundary conditions are not usually seen in experiments, but are much more natural to compute with, and the results are unchanged for large systems.…”