2021
DOI: 10.1039/d1sc04806f
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A metal-free 2D layered organic ammonium halide framework realizing full-color persistent room-temperature phosphorescence

Abstract: Organic-inorganic hybrid metal halides have attracted intensive attention because of their unique electronic structure and solution processability. They have rigid micro/nano structure and heavy atom effect, which has obvious advantages...

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Cited by 42 publications
(29 citation statements)
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“…57–59 On the other hand, Br − ⋯H + hydrogen interactions can inhibit the molecular vibrational movement which improves the luminescence properties. 60 As shown in the structure description section, the XRD results demonstrate the existence of C–H⋯π and Br⋯π interactions between the different organic molecules (see Fig. S2 and S3†).…”
Section: Resultsmentioning
confidence: 65%
“…57–59 On the other hand, Br − ⋯H + hydrogen interactions can inhibit the molecular vibrational movement which improves the luminescence properties. 60 As shown in the structure description section, the XRD results demonstrate the existence of C–H⋯π and Br⋯π interactions between the different organic molecules (see Fig. S2 and S3†).…”
Section: Resultsmentioning
confidence: 65%
“…In particular, the development of metal-free perovskites with white light emission is also a promising direction. 136…”
Section: Discussionmentioning
confidence: 99%
“…In particular, the development of metal-free perovskites with white light emission is also a promising direction. 136 (4) In-depth understanding about the photophysical mechanism of white emission. The broad-band white light emission of OIHPs often contains multiple emission centers derived from inorganic or/and organic excitons.…”
Section: Discussionmentioning
confidence: 99%
“…Similarly, the flexible material design of doping systems makes it easy to realize colourful OPL emission by changing the guest molecules. 95,96 Remarkably, ultralong luminescence with emission lifetimes greater than 1 hour can be achieved in pure organic doping systems. 32,92,97–99…”
Section: Design and Classification Of Halide-containing Opl Materials...mentioning
confidence: 99%