2006
DOI: 10.1121/1.2195292
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A method for modeling polymer viscoelastic data and the temperature shift function

Abstract: Dynamic viscoelastic polymer data is traditionally time-temperature shifted to obtain a temperature shift function (TSF) and then fitted to various analytical models. The process of obtaining the TSF can introduce considerable procedural or operator bias. Nevertheless the Havriliak and Negami (HN) model using the TSF methodology can generally describe polymers that are rheologically simple. In this paper the “wicket” plot is utilized as an important tool in analyzing data, as it is completely independent of ti… Show more

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Cited by 33 publications
(12 citation statements)
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“…Therefore, instead of the sigmoidal function, a complex modulus model proposed by Havriliak and Negami [32] was adopted to accomplish this manipulation in the present study. The Havriliak-Negami (HN) model has been able to accurately simulate the mechanical relaxation behavior of polymer materials in the frequency domain [33][34][35]. However, very limited research has been reported on modeling LVE behavior of asphalt concrete with the HN model.…”
Section: Havriliak-negami Modelmentioning
confidence: 99%
“…Therefore, instead of the sigmoidal function, a complex modulus model proposed by Havriliak and Negami [32] was adopted to accomplish this manipulation in the present study. The Havriliak-Negami (HN) model has been able to accurately simulate the mechanical relaxation behavior of polymer materials in the frequency domain [33][34][35]. However, very limited research has been reported on modeling LVE behavior of asphalt concrete with the HN model.…”
Section: Havriliak-negami Modelmentioning
confidence: 99%
“…However, parameters of these laws are often determined by curve-fitting [42] in order to best superimpose the isotherms and they can have poor precision. In the present paper, we have determined it along with the parameters of the viscoelastic model (as it is done by some authors [43,44]). As underlined in [45], the calculated shift coefficients with this last method have a physical meaning since the viscoelastic model is supposed to verify some conditions such as causality [46].…”
Section: Accepted Manuscript N O T C O P Y E D I T E Dmentioning
confidence: 98%
“…The elastic constants are independent of temperature and the time constatnts have the same dependence of temperature. The isotherms of dynamic modulus can be shifted into a unique master curve by using the horizontal shift factor [28][29][30]. When the Cole-Cole plot and the Black diagram are temperature dependent, the material does not exhibit simple thermorheological behavior.…”
Section: Applicablity Of the Time-temperature Superposition Principlementioning
confidence: 99%