For engineering structures, there is a strong need to assign natural frequencies to achieve desired dynamic performance. This study proposes a receptance-based frequency assignment method for assembled structures. Very often, the substructures involved are not allowed or are difficult to change. This method uses the links between the substructures as targets of structural modifications and determines the structural properties of the links that assign the desired frequencies cast as an optimisation problem. These links could be either simple discrete structural components such as masses and springs or complex continuous structures. Only a few receptances of the substructures are required in this method, which can be measured accurately and easily in practice. Two numerical examples are presented to show the validity of this method and its strength in dealing with complex assembled structures.