A method to account for the effect of hydrodynamics on polar organic compound uptake by passive samplers

Booij, Kees; Maarsen, Natasja L.; Theeuwen, Matthijs; Bommel, Ronald van

doi:10.1002/etc.3700

Cited by 41 publications

(45 citation statements)

References 41 publications

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“…To further assess the likelihood of flow effects on R s , k w was measured by the alabaster plate dissolution method (Booij et al 2017), both inside and outside the canister (Figure 4). Valid k w measurements could be made at flow velocities between 8 and 27 cm/s, at temperatures between 7 and 21 °C.…”

Section: Resultsmentioning

confidence: 99%

“…Valid k w measurements could be made at flow velocities between 8 and 27 cm/s, at temperatures between 7 and 21 °C. Values at U = 0 are shown for completeness, but are not valid because dissolution rates at low flow conditions are controlled by density currents that originate from the dissolution process itself (Booij et al 2017). The canister attenuated k w by a factor of 2.1 ± 0.5 (Figure 5).…”

Section: Resultsmentioning

confidence: 99%

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POCIS Calibration for Organic Compound Sampling in Small Headwater Streams

Booij¹,

Chen

Trask

2020

Enviro Toxic and Chemistry

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Field‐based atrazine sampling rates (Rs) obtained by the polar organic chemical integrative sampler (POCIS) method were measured in 9 headwater streams over 3 yr covering 5 to 6 exposure periods of 2 to 3 wk/site/yr. Rates were best in line with the model Rs = 148 mL/d, with a standard deviation of 0.17 log units (factor 1.5). The POCIS canisters reduced mass transfer coefficients of the water boundary layer by a factor of 2 as measured by alabaster dissolution rates. A mechanistic model that accounts for flow and temperature effects yielded a fair estimate of the effective exchange surface area (12.5 ± 0.8 cm2). This model could only be tested for higher flow velocities because of uncertainties associated with the measurement of flow velocities <1 cm/s. Pictures of sorbent distributions in POCIS devices showed that the effective exchange surface area varied with time during the exposures. Error analysis indicated that sorbent distributions and chemical analysis were minor error sources. Our main conclusion is that an atrazine sampling rate of 148 mL/d yielded consistent results for all 3 yr across 9 headwater streams. Environ Toxicol Chem 2020;39:1334–1342. © 2020 SETAC

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

POCIS Calibration for Organic Compound Sampling in Small Headwater Streams

Booij¹,

Chen

Trask

2020

Enviro Toxic and Chemistry

Self Cite

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“…According to the method reported by Booij et al [16], flow velocities were calculated from the measured mass transfer coefficients of the water boundary layer near the surface of the POCIS devices with alabaster plates. This is because the flow velocity measured by commercial equipment or calculated by volumetric pump output does not represent the exact value of the flow velocity near the POCIS surface.…”

Section: Flow Velocity Determinationmentioning

confidence: 99%

Validation of the Application of a Polar Organic Chemical Integrative Sampler (POCIS) in Non-steady-state Conditions in Aquatic Environments

Noro

Yabuki

Banno

et al. 2019

J. of Wat. & Envir. Tech.

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This study validated the chemicals monitoring ability of a polar organic chemical integrative sampler (POCIS) under non-steady-state conditions resulting from natural disasters and environmental accidents in aquatic environments via laboratory experiments. The goal of this work was to contribute toward monitoring the actual state of chemical contamination resulting from emergencies and natural disasters. A chamber replicating the chemical contamination of an aquatic environment established by a chemical exposure assessment model was set up in a clean booth. The concentrations of seven neonicotinoid pesticides were increased to a maximum of 1,000, 100, or 10 µg/L for one day and decreased by 50% per day thereafter. A POCIS was set up with polyethersulfone as the permeation membrane and a resin (Oasis hydrophilic-lipophilic balance) as the receiving phase. Calibration tests of the POCIS were also conducted. The results of this study led to the addition of six neonicotinoid pesticides to the list of POCIS-measurable targets. The results of the chamber experiments showed that a POCIS is a good tool for chemicals monitoring under non-steady-state conditions in an aquatic environment.

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“…A third option is to apply a model that takes the mass transfer coefficient of the water boundary ( k w ) layer into account

\frac{1}{R_{normals}} = \frac{1}{R_{s, \max}} + \frac{1}{{A k}_{normalw}}

where R s,max is the limiting R s at infinite flow, and A is the sampler's surface area. Values of k w may be obtained by direct measurement or by applying a k w – U relationship (e.g., for mass transfer from a flat plate under laminar flow; Booij et al ).…”

Section: Introductionmentioning

confidence: 99%

Review of atrazine sampling by polar organic chemical integrative samplers and Chemcatcher

Booij¹,

Chen

2018

Enviro Toxic and Chemistry

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A key success factor for the performance of passive samplers is the proper calibration of sampling rates. Sampling rates for a wide range of polar organic compounds are available for Chemcatchers and polar organic chemical integrative samplers (POCIS), but the mechanistic models that are needed to understand the effects of exposure conditions on sampling rates need improvement. Literature data on atrazine sampling rates by these samplers were reviewed with the aim of assessing what can be learned from literature reports of this well-studied compound and identifying knowledge gaps related to the effects of flow and temperature. The flow dependency of sampling rates could be described by a mass transfer resistance model with 1 (POCIS) or 2 (Chemcatcher) adjustable parameters. Literature data were insufficient to evaluate the temperature effect on the sampling rates. An evaluation of reported sampler configurations showed that standardization of sampler design can be improved: for POCIS with respect to surface area and sorbent mass, and for Chemcatcher with respect to housing design. Several reports on atrazine sampling could not be used because the experimental setups were insufficiently described with respect to flow conditions. Recommendations are made for standardization of sampler layout and documentation of flow conditions in calibration studies. Environ Toxicol Chem 2018;37:1786-1798. © 2018 SETAC.

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A method to account for the effect of hydrodynamics on polar organic compound uptake by passive samplers

Cited by 41 publications

References 41 publications

POCIS Calibration for Organic Compound Sampling in Small Headwater Streams

POCIS Calibration for Organic Compound Sampling in Small Headwater Streams

Validation of the Application of a Polar Organic Chemical Integrative Sampler (POCIS) in Non-steady-state Conditions in Aquatic Environments

Review of atrazine sampling by polar organic chemical integrative samplers and Chemcatcher

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