“…45 Consequently, Janus structures based on the MA 2 Z 4 family of innovative penta-atomic layers, such as XMAZ 2 (X = O, S, Se, Te; M = Cr, Mo, W, Ti; A = Si, Ge; Z = N, P, As), have been theoretically predicted to exhibit exceptional properties. [45][46][47][48][49][50][51] These materials showcase outstanding photocatalytic, piezoelectric, Rashba-type spin splitting, and tunable electronic properties. As a result, they hold significant potential for wide-ranging applications in electronic and optoelectronic devices.…”