SummaryExperiments were performed to investigate the flame thickness of the upward flame on the poly(methyl methacrylate) slabs with width of 100-400 mm. The results indicated that the flame thickness exhibited an increase first and then decrease trend in the upright orientation, and the maximum thickness location was approximately equal to the pyrolysis front location. The thickness of the flame along the lateral side of slab was less than that of the interior flame. The flame maximum thickness as a function of pyrolysis height and width was obtained, which showed the maximum thickness provided a power law increase with the pyrolysis height and width. Furthermore, the maximum thickness exhibited a power law increase with the total heat release rate as well. Based on the obtained flame thickness, the radiation heat flux at the pyrolysis height was The flame height correlation as shown in Equations 1 and 2 were obtained based on theoretical analysis and experimental data 4-9where a, b, and n are constants, x fl is the flame height, x p is the pyrolysis height, and _ Q ′ is the heat release rate (HRR) per unit width. However, the previous researches mentioned above did not consider the