The experimental evidence for the realization of a superplastic behavior with 900% elongation in V-alloyed high-nitrogen austenitic Fe-19Cr-22Mn-1.5V-0.3C-0.6N steel was proposed. Using thermomechanical processing, a misoriented grain/subgrain austenitic microstructure with a high density of deformation-assisted defects and precipitates was developed in the steel. During high-temperature tensile deformation in a temperature interval from 850 to 1000 • C and strain-rate range from 4 × 10 −4 s −1 to 6 × 10 −3 s −1 , this microstructure demonstrated the characteristics of superplastic flow: elongation in the interval 400-900%, strain-rate sensitivity exponent m = 0.40-0.49, grain boundary sliding mechanism. The maximum elongation to failure (900%) was reached at deformation temperature 950 • C and strain rate 4 × 10 −4 s −1 .precipitation hardening [24][25][26][27]. Despite the visible advantages of the high-nitrogen austenitic steels as a construction material, there is limited data related to the possibility of realization of superplastic flow in them. Padmanabhan [1] mentioned a result of N. Narkevich, who reported 239% elongation in Fe-20Cr-20Mn-4.7V-1.14N (mass.%) steel tested at temperature 950 • C and strain-rate 4.6 × 10 −4 s −1 . Such relatively high elongation was obtained for the steel after a solid-solution treatment followed by 50% cold-rolling and age-hardening at 700 • C for 1 h. The microstructure of the steel during high-temperature tests, probably, was not strictly single-phase austenitic but also contained Cr-based and V-based nitrides. This result lied in line with those for single-phase austenitic stainless steels, in which the superplastic-assisted elongation does not exceed 280% [1,28]. Mineura [29] reported much higher elongation (527%) for Fe-20Cr-10Ni-0.7N (mass.%) steel at temperature 800 • C and strain rate 8 × 10 −4 s −1 . They used two-step cold rolling with intermediate anneal at 1000 • C for obtaining fine-grained austenitic structure stabilized by fine chromium nitrides. Vanadium-alloying promotes a homogeneous (continuous) reaction of precipitate hardening in austenitic CrMn steels [24], and this fact could provide higher stability of the fine-grained structure during high-temperature tests as compared to chromium nitrides. Therefore, there is a potential for improvement of the values for the superplastic elongation obtained by Mineura [29].This paper aimed to find out the superplastic characteristics in high-nitrogen V-alloyed austenitic steel Fe-19Cr-22Mn-1.5V-0.3C-0.6N (mass.%).