We study gamma-ray line signatures from electroweakly interacting non-abelian spin-1 dark matter (DM). In this model, Z2-odd spin-1 particles including a DM candidate have the SU(2)L triplet-like features, and the Sommerfeld enhancement is relevant in the annihilation processes. We derive the annihilation cross sections contributing to the photon emission and compare with the SU(2)L triplet fermions, such as Wino DM in the supersymmetric Standard Model. The Sommerfeld enhancement factor is approximately the same in both systems, while our spin-1 DM predicts the larger annihilation cross sections into γγ/Zγ modes than those of the Wino by $$ \frac{38}{9} $$
38
9
. This is because a spin-1 DM pair forms not only J = 0 but also J = 2 partial wave states where J denotes the total spin angular momentum. Our spin-1 DM also has a new annihilation mode into Z2-even extra heavy vector and photon, Z′γ. For this mode, the photon energy depends on the masses of DM and the heavy vector, and thus we have a chance to probe the mass spectrum. The latest gamma-ray line search in the Galactic Center region gives a strong constraint on our spin-1 DM. We can probe the DM mass for ≲ 25.3 TeV by the Cherenkov Telescope Array experiment even if we assume a conservative DM density profile.