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AbstractWe report a new model relating porosity and formation resistivity factor. This model not only explains both Archie and non-Archie behaviors with non-conductive minerals, but also complies with meaningful physical bounds. We define an equivalent rock element aligned with the direction of measurement, in which the pore structure is comprised of two orthogonal components. One is oriented along electrical potential gradient and contributes most efficiently to current flow. The other is perpendicular to the gradient and contributes least efficiently per unit pore volume. The ratio of the former over the latter is defined as "pore structure efficiency". By adjusting pore structure efficiency, any rock can be equivalently represented. Formation resistivity factor can then be expressed as a function of total porosity and pore structure efficiency. Upon analyzing relevant factors in reservoir rocks, we approximate pore structure efficiency as a simple linear or power function of porosity. This leads to a new theoretical relationship between formation resistivity factor and porosity that:(1) explains and agrees with Archie's generalized first equation for a geologically realistic porosity range from 0 to 40%, (2) explains non-Archie phenomena, e.g. noticeable curvature in dual logrithm coordinate space of formation factor versus porosity, (3) is consistent with physical bounds from 0 to 100% porosity, e.g., the magnitude of slope is never smaller than 1, and tends to be 1 as porosity approaches 100%, (4) generalizes multiple porosity domain system into one transitionally smooth description, (5) contains a term representing pore structure efficiency independent of porosity that can be potentially used for fracture analysis, (6) is applicable to both isotropic and anisotropic media by definition. Fig. 1-The straight tube model. The only pore is a straight tube. The formation resistivity factor is F=1/φ. The efficient electrical porosity is the same as total porosity. P p Pf Pf Equivalent Rock Element Model in 2D view Electrical Potential Gradient P p Pf Pf Equivalent Rock Element Model in 2D view Electrical Potential Gradient Fig. 2-Equivalent rock element model. The pore space is comprised of two components, one parallel and the other perpendicular to electrical potential gradient.