A Molecular Description of Hydrogel Forming Polymers for Cement-Based Printing Paste Applications

Abstract

This research endeavors to link the physical and chemical characteristics of select polymer hydrogels to differences in printability when used as printing aids in cement-based printing pastes. A variety of experimental probes including differential scanning calorimetry (DSC), NMR-diffusion ordered spectroscopy (DOSY), quasi-elastic neutron scattering (QENS) using neutron backscattering spectroscopy, and X-ray powder diffraction (XRD), along with molecular dynamic simulations, were used. Conjectures based on objective measures of printability and physical and chemical-molecular characteristics of the polymer gels are emerging that should help target printing aid selection and design, and mix formulation. Molecular simulations were shown to link higher hydrogen bond probability and larger radius of gyration to higher viscosity gels. Furthermore, the higher viscosity gels also produced higher elastic properties, as measured by neutron backscattering spectroscopy.

Gels: Synthesis, Characterization and Applications in High Performance Chemistry

“…Molecular simulations were shown to link a higher hydrogen bond probability and larger radius of gyration to higher-viscosity gels. Furthermore, the higher-viscosity gels also produced higher elastic properties, as measured by neutron backscattering spectroscopy [ 9 ].…”