The thermal and mechanical properties of bricks are strongly dependent on both the chemical composition and the microstructural features of the used fired clay material. Focussing on the latter, we here identify, in terms of volume fraction, shape, and orientation characteristics, one-to-several micrometer-sized subdomains (''material phases'') within the SEM-imaged microstructure of two raw clays fired at 880 and 1100 centigrades: (1) quartz grains, (2) muscovite, (3) Fe-Mg mica, (4) feldspar grains, (5) decarbonated dolomite, (6) pores, or (7) binding matrix. This identification rests on the simultaneous use of Scanning Electron Microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDX), with correspondingly obtained data entering statistical analyses based on the Otsu algorithm, and complemented by minimum grain size and grain shape requirements, as well as by logical exclusion criteria. Crystalline and amorphous phase shares were additionally confirmed by X-ray powder diffraction measurements (PXRD). As for the investigated clays, an increased firing temperature results in dehydroxylation of muscovite, and in a reduced appearance of feldspar grains.