We present optical and near-infrared stellar polarization observations toward the dark filamentary clouds associated with IC5146. The data allow us to investigate the dust properties (this paper) and the magnetic field structure (Paper II). A total of 2022 background stars were detected in R c -, i ′ -, H-, and/or K-bands to A V 25 mag. The ratio of the polarization percentage at different wavelengths provides an estimate of λ max , the wavelength of peak polarization, which is an indicator of the small-size cutoff of the grain size distribution. The grain size distribution seems to significantly change at A V ∼ 3 mag, where both the average and dispersion of P Rc /P H decrease. In addition, we found λ max ∼ 0.6-0.9 µm for A V > 2.5 mag, which is larger than the ∼ 0.55 µm in the general ISM, suggesting that grain growth has already started in low A V regions. Our data also reveal that polarization efficiency (PE ≡ P λ /A V ) decreases with A V as a power-law in R c -, i ′ -, and K-bands with indices of -0.71±0.10, -1.23±0.10 and -0.53±0.09. However, H-band data show a power index change; the PE varies with A V steeply (index of -0.95±0.30) when A V < 2.88 ± 0.67 mag but softly (index of -0.25±0.06) for greater A V values. The soft decay of PE in high A V regions is consistent with the Radiative Aligned Torque model, suggesting that our data trace the magnetic field to A V ∼ 20 mag. Furthermore, the breakpoint found in H-band is similar to the A V where we found the P Rc /P H dispersion significantly decreased. Therefore, the flat PE-A V in high A V regions implies that the power index changes result from additional grain growth.