Near-field radiative heat transfer (NFRHT) between dissimilar materials supporting surface polaritons in the infrared is of critical importance for applications such as photonic thermal rectification and near-field thermophotovoltaics. Here, we measure NFRHT between millimetersize surfaces made of 6H-SiC and doped Si, respectively supporting surface phonon-polaritons (SPhPs) and surface plasmon-polaritons (SPPs) in the infrared, separated by a 150-nm-thick vacuum gap spacing maintained via SiO2 nanopillars. For purpose of comparison, measurements are also performed between two doped Si surfaces. The measured radiative flux is in good agreement with theoretical predictions based on fluctuational electrodynamics. A flux enhancement beyond the blackbody limit of ~ 8.2 is obtained for the SiC-Si sample, which is smaller than the enhancement for the Si-Si sample (~ 12.5) owing to the spectral mismatch of the SiC and Si light lines, and SPhP and SPP resonances. However, due to lower losses in SiC than Si and weaker SPhP-SPP coupling than SPP coupling, the near-field enhancement for the SiC-Si sample exhibits a more pronounced monochromatic behavior with a resonant flux that is ~ 5 times larger than the resonant flux for the Si-Si sample. This work demonstrates that it is possible to modulate NFRHT via surface polariton coupling, and will accelerate the development of energy 2 conversion and thermal management devices capitalizing on the near-field effects of thermal radiation between dissimilar materials. KEYWORDS: near-field radiative heat transfer, radiative flux measurement, dissimilar materials, coupled surface phonon-and plasmon-polaritons, silicon carbide, doped silicon 3 Near-field radiative heat transfer (NFRHT), arising when heat sources are separated by subwavelength gap spacings, can significantly exceed Planck's blackbody limit owing to tunneling of evanescent waves. 1-6 These evanescent waves include broadband frustrated modes and narrowband surface polaritons that can lead to quasi-monochromatic radiative flux. 7 Many potential applications of NFRHT, such as near-field thermophotovoltaics, 8-12 photonic thermal rectification 13,14 and flux modulation, 15 capitalize on the coupling of surface polaritons between dissimilar materials. Measurements of NFRHT between dissimilar materials in the microsize sphere-surface (SiO2-Si, 16 SiO2-Au 17 ) and microsize mesa-surface (SiO2-Au, 18 Si- VO2 14 ) configurations have been performed. However, from an application standpoint, the ability to demonstrate NFRHT between macroscale surfaces (~ mm 2 ) is critical, since the heat transfer rate is not only proportional to the near-field enhancement of the radiative flux, but also to the size of the surfaces. NFRHT measurements between macroscale surfaces made of the same materials, namely Si, [19][20][21][22] SiO2, 23-27 Al2O3, 28 Al, 29 graphene, 30 graphene-covered SiO2 31 , and metallodielectric multilayers 32 have been reported. Only Ito et al. 33 measured NFRHT between macroscale surfaces made of dissimilar materials ...