A new 3D cadmium coordination polymer containing 3-amino-1H-1,2,4-triazole: Synthesis, structure, and property

Energetic Salts of Sensitive N,N′-(3,5-Dinitropyrazine-2,6-diyl)dinitramide Stabilized through Three-Dimensional Intermolecular Interactions

“…Over the past two decades, explosive growth of high-energy-density materials based on derivatives of five- or six-membered azines has occurred. − Energetic metal–organic frameworks (EMOFs) assembled from metallic nodes with nitrogen-rich azines have gained much interest because of their dense crystalline structures. − The preparation of EMOFs has undergone substantial advancement, from one-dimensional (1D) and two-dimensional (2D) EMOFs to the emergence of three-dimensional (3D) EMOFs. − Moreover, these 3D energetic frameworks possess more complex linking modes in comparison with 1D linear and 2D layered structures, which improves their structural reinforcement and molecular stabilities. − Nowadays, these 3D EMOFs play a central role in modern energetics because of their prevalent occurrence across a broad range of applications such as explosives, oxidizers, and pyrotechnics. , New EMOFs should preferably have good detonation properties, high density, and good thermal stability, along with ease of synthesis, high atom economy, and waste prevention. Therefore, tuning the structures and physicochemical properties of existing energetic structures by tailoring their properties for required applications is highly desirable …”