“…First discovered by Davy (1811), clathrate hydrates long remained a scientific curiosity and attracted considerable attention only after being found responsible for pipeline obstructions in oil production (Sloan and Koh, 2007). Hydrate formation is potentially beneficial in other instances, however, such as natural gas storage Thomas and Dawe, 2003;Khokhar et al, 1998;Kumar et al, 2008;Sloan, 2003), CO 2 capture and sequestration (Yamasaki et al, 2000;Saji et al, 1992;Mondal et al, 2012;Ho et al, 2013;Babu et al, 2013;Lee et al, 2010;Linga et al, 2007a), gas separation (Kamata et al, 2005;Lee et al, 2009;Cha et al, 2010), H 2 storage (Florusse et al, 2004;Strobel et al, 2006;Lee, H. et al, 2005;Anderson et al, 2007) and desalination (Bradshaw et al, 2007;Niblock, 1998, 2000;Cha and Seol, 2013;Park et al, 2011;Mccormack and Ripmeester, 2013), which encourages further studies on the thermodynamic stability and formation rates of hydrates so that economically viable hydrate-based processes could be developed.…”