2024
DOI: 10.1002/ange.202317482
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A New Architecture for DNA‐Templated Synthesis in Which Abasic Sites Protect Reactants from Degradation

Jennifer Frommer,
Robert Oppenheimer,
Benjamin M. Allott
et al.

Abstract: The synthesis of artificial sequence‐defined polymers that match and extend the functionality of proteins is an important goal in materials science. One way of achieving this is to program a sequence of chemical reactions between precursor building blocks by means of attached oligonucleotide adapters. However, hydrolysis of the reactive building blocks has so far limited the length and yield of product that can be obtained using DNA‐templated reactions. Here, we report an architecture for DNA‐templated synthes… Show more

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