A new assembly of a Wells-Dawson polyoxometalate-based iron(III) coordination complex hybrid: Synthesis, crystal structure, thermal and electrochemical properties

Hammami, Imen; Dhifallah, Fatma; Ouari, Kamel; Belkhiria, Mohamed Salah; Nasri, Habib

doi:10.1016/j.poly.2018.12.034

Cited by 6 publications

(2 citation statements)

References 27 publications

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“…The Fe2−Cl3 bond distances are identical=2.186 (8) Å and the bond angles vary from 108.55° to 109.93°. These data are in agreement with those observed in literature [33–35] …”

Section: Resultssupporting

confidence: 94%

“…These data are in agreement with those observed in literature. [33][34][35] The calculated average values of the distortion indices as described by Baur [36] correspond to the different lengths and angles in the (FeCl 6 ) octahedra and (FeCl 4 ) tetrahedra, were X=Cl, m the average values and ID (Fe1À X) = 0.00687, ID (XÀ Fe1À X) = 0.0923. While ID (Fe2À X) = 0, ID (XÀ Fe2À X) = 0.…”

Section: Crystal Structurementioning

confidence: 99%

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Structural Study, Spectroscopic Characterization and Evaluation of the Antimicrobial Behavior of a New Fe (III) Organic‐Inorganic Hybrid Material: (C₈H₁₄N₂)₄[(FeCl₆)(FeCl₄)]Cl₄

Essghaier,

Methamem,

Faouzi Zid

et al. 2023

ChemistrySelect

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Due to the increasing demand for novel antimicrobials agents to treat microbial infections, the current work, focused on the synthesis of new agents owing innovative chemistry and modes of action. We describe an organic‐inorganic hybrid compound with the formula (C8H14N2)4[(FeCl6)(FeCl4)]Cl4, it was synthesized via slow evaporation at room temperature, and characterized using various techniques. The compound crystallizes in the tetragonal system, with I41/a space group. In the crystal structure, the organic layers are made up of protonated m‐Xylylene diamine (C8H14N2)2+ creating between them free tunnels, in which inorganic entities can be placed. These entities contain one octahedral (FeCl6)3− ion, one tetrahedral (FeCl4)−, and uncoordinated chlorine anions. Crystal cohesion is achieved through N−H…Cl hydrogen bonds and Cl…Cl interactions. The UV‐vis spectroscopy was investigated and the optical band gap energy 2.00 eV suggests the semiconductor behavior of the title compound. The functional groups present in the crystal structure were performed by FTIR spectroscopy. Thermal analysis was also carried out. Analysis of the Hirshfeld surface revealed that the H…Cl/Cl…H interactions dominate the structure (74 %). The new Fe(III) complex gave strong antibacterial potential against S. aureus, E. coli, M. luteus, it was able to inhibit growth of Candida species and Trichophyton intergiditale and showing lysozyme activity.

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“…The Fe2−Cl3 bond distances are identical=2.186 (8) Å and the bond angles vary from 108.55° to 109.93°. These data are in agreement with those observed in literature [33–35] …”

Section: Resultssupporting

confidence: 94%

Section: Crystal Structurementioning

confidence: 99%

Structural Study, Spectroscopic Characterization and Evaluation of the Antimicrobial Behavior of a New Fe (III) Organic‐Inorganic Hybrid Material: (C₈H₁₄N₂)₄[(FeCl₆)(FeCl₄)]Cl₄

Essghaier,

Methamem,

Faouzi Zid

et al. 2023

ChemistrySelect

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Design and Strategies to Enhance the Electrochemical Properties ofPOMNanomaterials for Electrocatalysis

Dada,

Jones,

Walsh

et al. 2024

Applied Polyoxometalate‐based Electrocatalysis

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Green complexation for removal of Ni2+ from synthetic effluents by a nanomaterial polyoxometalate

Zabat

2022

Current Research in Green and Sustainable Chemistry

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A new assembly of a Wells-Dawson polyoxometalate-based iron(III) coordination complex hybrid: Synthesis, crystal structure, thermal and electrochemical properties

Cited by 6 publications

References 27 publications

Structural Study, Spectroscopic Characterization and Evaluation of the Antimicrobial Behavior of a New Fe (III) Organic‐Inorganic Hybrid Material: (C₈H₁₄N₂)₄[(FeCl₆)(FeCl₄)]Cl₄

Structural Study, Spectroscopic Characterization and Evaluation of the Antimicrobial Behavior of a New Fe (III) Organic‐Inorganic Hybrid Material: (C₈H₁₄N₂)₄[(FeCl₆)(FeCl₄)]Cl₄

Design and Strategies to Enhance the Electrochemical Properties ofPOMNanomaterials for Electrocatalysis

Green complexation for removal of Ni2+ from synthetic effluents by a nanomaterial polyoxometalate

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A new assembly of a Wells-Dawson polyoxometalate-based iron(III) coordination complex hybrid: Synthesis, crystal structure, thermal and electrochemical properties

Cited by 6 publications

References 27 publications

Structural Study, Spectroscopic Characterization and Evaluation of the Antimicrobial Behavior of a New Fe (III) Organic‐Inorganic Hybrid Material: (C8H14N2)4[(FeCl6)(FeCl4)]Cl4

Structural Study, Spectroscopic Characterization and Evaluation of the Antimicrobial Behavior of a New Fe (III) Organic‐Inorganic Hybrid Material: (C8H14N2)4[(FeCl6)(FeCl4)]Cl4

Design and Strategies to Enhance the Electrochemical Properties ofPOMNanomaterials for Electrocatalysis

Green complexation for removal of Ni2+ from synthetic effluents by a nanomaterial polyoxometalate

Contact Info

Product

Resources

About

Structural Study, Spectroscopic Characterization and Evaluation of the Antimicrobial Behavior of a New Fe (III) Organic‐Inorganic Hybrid Material: (C₈H₁₄N₂)₄[(FeCl₆)(FeCl₄)]Cl₄

Structural Study, Spectroscopic Characterization and Evaluation of the Antimicrobial Behavior of a New Fe (III) Organic‐Inorganic Hybrid Material: (C₈H₁₄N₂)₄[(FeCl₆)(FeCl₄)]Cl₄