A new chain-like heteropolytungstate formed by Keggin cluster units: Synthesis and structure of [H2bpy]3[SiMnW11O39]·1.25H2O

Meng, Jing; Ma, Ying; Xu, Xin; Li, Yang Guang; Wang, Enbo

doi:10.1016/j.cclet.2006.11.020

Chinese Chemical Letters

2007

DOI: 10.1016/j.cclet.2006.11.020

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A new chain-like heteropolytungstate formed by Keggin cluster units: Synthesis and structure of [H2bpy]3[SiMnW11O39]·1.25H2O

Jing Meng

Ying Ma

Xin Xu

et al.

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ChemInform Abstract: A New Chain‐Like Heteropolytungstate Formed by Keggin Cluster Units: Synthesis and Structure of [H₂bpy]₃ [SiMnW₁₁O₃₉]×1.25H₂O.

Meng

et al. 2008

ChemInform

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A New Chain-Like Heteropolytungstate Formed by Keggin Cluster Units: Synthesis and Structure of [H 2 bpy] 3 [SiMnW 11 O 39 ]·1.25H 2 O. -The title compound is hydrothermally synthesized from an aqueous solution containing K8[β2-SiW11O39]·14H2O, MnCl2, and 4,4'-bipyridine (autoclave, 130°C, 5 d, 39% yield). [H2bpy]3[SiMnW11O39]·1.25H2O crystallizes in the monoclinic space group P21/n with Z = 4 (single crystal XRD) and exhibits a new zigzag chain structure, which is different to the straight chain structure reported for one-dimensional transition metal substituted Keggin heteropolytungstates. Furthermore, the zigzag chains of the title compound form layers which are stacked parallel giving a three-dimensional structure with dumbbell-like one-dimensional channels. -(MENG, J. X.; MA, Y.; XU, X. X.; LI, Y. G.; WANG*, E. B.; Chin.

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ChemInform Abstract: A New Chain‐Like Heteropolytungstate Formed by Keggin Cluster Units: Synthesis and Structure of [H₂bpy]₃ [SiMnW₁₁O₃₉]×1.25H₂O.

Meng

et al. 2008

ChemInform

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Synthesis and structure of a pure inorganic polyoxo-metalate-based porous framework

Zhang

Wang

2012

Chinese Chemical Letters

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Supramolecular assembly of Keggin polyoxomolybdate and 2,2′-bipyridine generated in situ from a decarboxylation coupling reaction

Wang

Chi

et al. 2013

Chinese Chemical Letters

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A new chain-like heteropolytungstate formed by Keggin cluster units: Synthesis and structure of [H2bpy]3[SiMnW11O39]·1.25H2O

Cited by 5 publications

References 10 publications

ChemInform Abstract: A New Chain‐Like Heteropolytungstate Formed by Keggin Cluster Units: Synthesis and Structure of [H₂bpy]₃ [SiMnW₁₁O₃₉]×1.25H₂O.

ChemInform Abstract: A New Chain‐Like Heteropolytungstate Formed by Keggin Cluster Units: Synthesis and Structure of [H₂bpy]₃ [SiMnW₁₁O₃₉]×1.25H₂O.

Synthesis and structure of a pure inorganic polyoxo-metalate-based porous framework

Supramolecular assembly of Keggin polyoxomolybdate and 2,2′-bipyridine generated in situ from a decarboxylation coupling reaction

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A new chain-like heteropolytungstate formed by Keggin cluster units: Synthesis and structure of [H2bpy]3[SiMnW11O39]·1.25H2O

Cited by 5 publications

References 10 publications

ChemInform Abstract: A New Chain‐Like Heteropolytungstate Formed by Keggin Cluster Units: Synthesis and Structure of [H2bpy]3 [SiMnW11O39]×1.25H2O.

ChemInform Abstract: A New Chain‐Like Heteropolytungstate Formed by Keggin Cluster Units: Synthesis and Structure of [H2bpy]3 [SiMnW11O39]×1.25H2O.

Synthesis and structure of a pure inorganic polyoxo-metalate-based porous framework

Supramolecular assembly of Keggin polyoxomolybdate and 2,2′-bipyridine generated in situ from a decarboxylation coupling reaction

Contact Info

Product

Resources

About

ChemInform Abstract: A New Chain‐Like Heteropolytungstate Formed by Keggin Cluster Units: Synthesis and Structure of [H₂bpy]₃ [SiMnW₁₁O₃₉]×1.25H₂O.

ChemInform Abstract: A New Chain‐Like Heteropolytungstate Formed by Keggin Cluster Units: Synthesis and Structure of [H₂bpy]₃ [SiMnW₁₁O₃₉]×1.25H₂O.