“…The [M+H] + precursor ions at m/z 933.4685, 1063.5327, 917.4743, 1081.5437, 919.4748, 593.1922, 1197.5886, 1047.5362, and 1033.5201 were found in peak 10, peaks 15–16, peak 18, peaks 20–23, and peak 27, respectively. Based on their fragment ions, combined with the retention time in reverse chromatography, and by comparison with the established database of FT, peak 10, peaks 15–16, peak 18, peaks 20–23, and peak 27 were identified as tribufuroside J , 26‐ O ‐β‐ D ‐glucopyranosyl‐(25S)‐5α‐furostan‐12‐one‐20(22)‐en‐3β,26‐diol‐3‐ O ‐β‐ D ‐glucopyranosyl‐(1→4)‐[α‐ L ‐rhamnopyranosyl‐(1→2)]‐β‐ D ‐galactopyranoside , 26‐ O ‐β‐ D ‐glucopyranosyl‐(25R)‐5α‐furostan‐12‐one‐20(22)‐en‐3β,26‐diol‐3‐ O ‐β‐ D ‐glucopyranosyl‐(1→4)‐β‐ D ‐galactopyranoside , 26‐ O ‐β‐ D ‐glucopyranosyl‐(25S)‐5α‐furostan‐20(22)‐en‐2α,3β,26‐triol‐3‐ O ‐β‐ D ‐galactopyranosyl‐(1→2)‐β‐ D ‐glucopyranosyl‐(1→2)‐β‐ D ‐galactopyranoside , 26‐ O ‐β‐ D ‐glucopyranosyl‐(25R)‐5α‐furostan‐20(22)‐en‐2α,3β,26‐triol‐3‐ O ‐β‐ D ‐glucopyranosyl‐(1→4)‐β‐ D ‐galactopyranoside , 26‐ O ‐β‐ D ‐glucopyranosyl‐(25S)‐5α‐furostan‐12‐one‐20(22)‐en‐3β,26‐diol , terrestrinin T , pseudoprotogracillin , and tribulosaponin A , respectively.…”