2015
DOI: 10.1007/s12034-015-0896-x
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A new green approach for the reduction of graphene oxide nanosheets using caffeine

Abstract: A simple and green chemistry approach for the preparation of reduced graphene oxide nanosheets was successfully demonstrated through the reduction of graphene oxide (GO) using caffeine as the reductant. Without using toxic and harmful chemicals, this method is environmentally friendly and suitable for the large-scale production of graphene. The samples of GO, before and after reduction with caffeine have been characterized by X-ray diffraction, Raman, Fourier transform infrared, X-ray photoelectron spectroscop… Show more

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Cited by 50 publications
(8 citation statements)
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“…GO is an oxidized version of graphene, having a broad range of oxygen functional groups such as carboxyl, hydroxyl, epoxy, and keto groups on its surface. , GO can be produced through chemical oxidation of graphite which is followed by successive exfoliation in water or organic solvents. , The synthetic recipe of GO formulates it as an electrochemical amalgam of both conductive π states from sp 2 carbon sites and the nonconducting σ states of its sp 3 bonded oxidized carbons . The presence of these oxygen functionalities make GO hydrophilic and insulating in nature. , Besides, GO also holds good colloidal conditions, , high surface area, enchanting mechanical properties, and remarkable optoelectronic hallmarks , and is easily processable due to its inherent structural attributes, although there are some obstructions in GO such as structural defects and poor electrical conductivity which can be restored through chemical, electrochemical, thermal, and green reduction. …”
Section: Introductionmentioning
confidence: 99%
“…GO is an oxidized version of graphene, having a broad range of oxygen functional groups such as carboxyl, hydroxyl, epoxy, and keto groups on its surface. , GO can be produced through chemical oxidation of graphite which is followed by successive exfoliation in water or organic solvents. , The synthetic recipe of GO formulates it as an electrochemical amalgam of both conductive π states from sp 2 carbon sites and the nonconducting σ states of its sp 3 bonded oxidized carbons . The presence of these oxygen functionalities make GO hydrophilic and insulating in nature. , Besides, GO also holds good colloidal conditions, , high surface area, enchanting mechanical properties, and remarkable optoelectronic hallmarks , and is easily processable due to its inherent structural attributes, although there are some obstructions in GO such as structural defects and poor electrical conductivity which can be restored through chemical, electrochemical, thermal, and green reduction. …”
Section: Introductionmentioning
confidence: 99%
“…With more disorder within the micro structure, the intensity of D band will be higher. The higher the ratio of the D band intensity to the G band intensity is, the worse the quality of generated graphene will be [163]. Figure 21 [164] shows the comparison of Raman spectrum of graphite, GO and rGO.…”
Section: Raman Testmentioning
confidence: 99%
“…The value of 2θ angle (diffraction angle) of characteristic peak shows the type of content and the intensity of peak represents the level of contents. Figure 23 [163],…”
Section: X-ray Diffraction (Xrd)mentioning
confidence: 99%
“…Graphene is one of the most sought after nanoparticles and it has been dubbed a 'miracle materials' due to its extraordinary physical and chemical properties [1] . Graphene is a hexagonal crystalline single layer of graphite with a C-C bond with distance of 0.142 nm.…”
Section: Introductionmentioning
confidence: 99%
“…Additionally, if its escape into the disposal waste system, it will create a detrimental environmental issue and also present a health hazard [18][19][20]. Owing to its harmful nature, the quest for a more environmentally friendly reductant is on demand [1].…”
Section: Introductionmentioning
confidence: 99%