Recent surveys show that wide (> 10 4 AU) binaries and triples are abundant in the field. We study the long-term evolution of wide hierarchical triple systems and the role played by the Galactic tidal (GT) field. We find that when the timescales of the secular von-Ziepel-Lidov-Kozai and the GT oscillations are comparable, the triple evolution becomes chaotic and extreme eccentricities can be attained. Consequently, the close pericentre approaches of the inner-binary components lead to strong interactions, and even mergers or collisions. We use a novel secular evolution code to quantify the key parameters of triple evolution coupled to GT, and carry out a population synthesis study of low and intermediate mass wide-orbit triples. We find that in ∼ 9% of low-mass wide-triples the inner main-sequence binaries collide or tidally-inspiral within 10 Gyr, with direct collisions 6 times more likely to occur than inspirals. For the intermediate mass sample, ∼ 7.6% of the systems merge or inspiral with roughly equal probabilities. We find the relative fractions of different stellar merger/inspiral outcomes as a function of their evolutionary stage (Main Sequence, MS; Red Giant, RG; or White Dwarf, WD), and discuss their transient electromagnetic signatures and the products of the merger/inspiral. In particular, we find the rate of WD-WD direct-collisions that lead to thermonuclear type-Ia Supernovae is comparable to other dynamical channels, and accounts for at most 0.1% of the total rate. RG inspirals provide a novel channel for formation of eccentric common-envelope-evolution binaries. We also find that the catalysis of mergers/collisions in triples due to GT could explain a significant fraction or even the vast majority of blue-stragglers in the field, produce progenitors for cataclysmic-variables, and give-rise to mergers and collisions of double-RG binaries.