A New Method for Group Analysis of Petroleum Fractions in Unconsolidated Porous Media

Abstract

A fast and accurate method for the group analysis of crude oils in porous media that describes petroleum components (especially heavy fractions) has been developed. NMR structure group analysis is used as the tool for the characterization of crude oils. This method is proposed as an alternative to existing complicated and laborious methods of characterization of extracted oil samples. Currently, group analysis of heavy fractions of crude oils is being investigated by means of chromatographic methods, such as the SARA (saturates-aromatics-resinsasphaltenes) test. These methods are usually expensive, and require considerable work from qualified personnel. Furthermore, these methods cannot be used for estimating the oil components in situ. The basis of determining crude oil components using NMR is the difference of the nuclei mobility in the different hydrocarbons during the NMR testing period. A combination of solvent extraction, NMR testing and data processing gives a series of NMR terms that are then used to specify hydrocarbon mixtures and their components both in the bulk phase and in unconsolidated porous media. Introduction NMR logging tools are currently used for determining reservoir properties such as porosity(1, 2), permeability(1-4), as well as mobile and immobile fluids(5-7). Recent developments in NMR research offer tools for separating water, oil, and gas from the combined NMR signal(7, 8). Very little is known about the use of NMR logging tools for the in situ characterization of crude oils(1). With respect to heavy oil and bitumen formations, NMR logging has not been very successful in characterizing crude oil. The reason for the lack of such success is the fact that the NMR logging tools cannot detect the spectra from most heavy oil and bitumen formations. It should be noted that high field NMR technology has solved such problems in the past, but such technology cannot be used downhole. A fundamental objective of the research performed in our laboratory is to extend the use of NMR logging tools to all heavy oil and bitumen formations. To this end, the NMR characteristics of heavy oils in porous media were investigated(9, 10). The objective of our work is to isolate the oil signal from the combined NMR spectrum of the formation, and then shift it towards the relaxation time range that can be detected by the conventional NMR logging tools. Once this goal is achieved, NMR logs of heavy oil and bitumen formations can become successful in the analysis of oil downhole. This objective was accomplished in the material presented in this paper through a series of experiments that addressed the following issues:Relaxation interactions in mixtures of simple organic liquids with water.Relaxation interactions in mixtures of simple organic liquids. Relaxation interactions in mixtures of simple organic liquids with solvents.Relaxation times of conventional crude oils with and without solvents present.Relaxation times of heavy crude oils and bitumen with and without solvents present.Relaxation times of heavy crude oils and bitumen with and without solvents in unconsolidated sands and with variable connate water saturation.

NMR relaxometry and diffusometry in characterizing structural, interfacial and colloidal properties of heavy oils and oil sands

“…However, the ranges are not constant and vary with oil viscosity and the amount and type of solvent used. It was shown that NMR analysis of heavy oil, both in bulk and in-situ, provided similar results for the percentages of saturates, asphaltenes, resins and aromatics in conventional SARA analyses [87]. However, the NMR method has the potential advantage over conventional techniques that it can be used in-situ and may have possible applications in downhole characterization.…”

“…In one study, an attempt was made to use NMR relaxation measurements to analyse petroleum fractions in unconsolidated porous media [87]. NMR can be used to determine oil components, as the mobility of the nuclei is different in the different hydrocarbons present.…”

Evaluation of Bitumen-Solvent Properties Using Low Field NMR

“…NMR measurements are simple and non-destructive, but capable of yielding an incredible wealth of information about the reservoir fluid under investigation in a particular sample (9) (10) . The mixture viscosity decreases dramatically as the ratio of the injected solvent to heavy oil or bitumen increases, and different solvents show different dilution capacity.…”

A 1H NMR method for the estimation of hydrogen content for all petroleum products

“…NMR spectroscopic technique has long been used for both qualitative (Gillet et al 1980;Kvalheim et al 1985) and quantitative (Srivastava 1982;Allen 1985;Abu-Dagga and Ruegger 1988;Smirnov et al 1992;Sarpal et al 1998;Bansal et al 2007;Bansal et al 2014;Mirotchnik et al 2001;Young and Galya 1984;Poveda and Molina 2012) studies of petroleum products. The main focus of these studies revolve around understanding the qualitative composition and to quantify average structural parameters such as aromatic and aliphatic content, average chain length for aliphatic moieties, and average number of substituents on the aromatic ring.…”