Abstract:In previous studies, we reported the stereoselective radical addition of organotin hydrides to unsaturated TADDOL diesters. These reactions occurred with intramolecular cyclization under inert atmosphere, radical initiator, toluene and 75°C with high yields and stereoselectivity depending on the reactivity and steric bulk of the organotin hydride employed. 1 Here, we decided to study a new method for the synthesis of these macrocycles through the radical addition of different triorganotin hydrides, R 3 SnH (R=… Show more
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