“…S3b,† the R ct values were found to be 5.559 and 2.286 kΩ for the SPGE and poly( l -Met)/SPGE, respectively. Furthermore, the apparent electron-transfer rate constant ( k app ) was calculated as follows: 23,24
where R denotes the universal gas constant (8.31447 J K −1 mol −1 ); T denotes the absolute temperature (298 K); n denotes the number of electrons transferred during the redox reaction; F denotes Faraday's constant (96 485 C mol −1 ); A denotes the surface area of the electrode (cm 2 ); R ct denotes the charge transfer resistance (Ω); and C denotes the concentration of [Fe(CN) 6 ] 3−/4− (5.0 × 10 −6 mol cm −3 ). From the calculation, the k app values were 1.496 × 10 −4 and 3.424 × 10 −4 cm s −1 for the SPGE and poly( l -Met)/SPGE, respectively.…”