A new organic‐inorganic molybdenum arsenate complex based on [(CuO₆)(As₃O₃)₂Mo₆O₁₈]^4‐ cluster as secondary building units

Abstract

+ complex cations. The electrochemical behavior of 1-modified carbon paste electrode (1-CPE) has been studied in detail.

Designing a new organic-inorganic arsenomolybdate by modification of traditional Keggin-type building fragment

“…[33]. The above conclusion can be also supported by previous reports [20][21][22][23][24][25][26][27][33][34][35][36][37][38][39], which are listed in table 2, and the representative complexes are shown in figure 1. 1,10-Phenanthroline serves as an inhibitor, preventing As III from being oxidized to some extent [24]. To investigate the effect of pH on final products, a series of parallel experiments have been carried out; 1 was obtained in the pH range of 5.0-6.5, the most optimal pH was 6.0.…”

The Anderson–Evans polyoxometalate: From inorganic building blocks via hybrid organic–inorganic structures to tomorrows “Bio-POM”

“…Structure analogues were also successfully obtained with [IMo 6 O 24 ] 5- [82]. Only a few Cu II /Zn II Mo 6 (7 and 5 crystal structures as of March 2015, respectively) compounds incorporating organic ligands have been reported based on both hydrothermal synthesis and conventional refluxing [225,226,230]. Interestingly, independently on the presence of organic counterpart, they all incorporate cyclic As 3 O 6 trimers that are capping the Cu/ZnO 6 octahedron on both sides of the Anderson-Evans cluster.…”

“…Mo 6 [93,175,[218][219][220], Co II/III Mo6 [221][222][223] FeIII Mo 6 [224], Cu II Mo6 [174,[225][226][227][228][229], Zn II Mo6 [230], AsIII Mo 6 [229][230][231][232],Mo 7 [112,176,193,[233][234][235][236][237][238][239][240][241][242][243][244][245], Te VI Mo6 [70,[246][247][248][249][250], Te VI W 6[70,75,[251][252]…”

Novel One-Dimensional Organic–Inorganic Polyoxometalate Hybrids Constructed from Heteropolymolybdate Units and Copper–Aminoacid Complexes

“…As a matter of fact, this lantern-shaped bis(As 3 O 3 )-capped Anderson-type arsenomolybdate is first discovered by Jeannin et al, where a Co-centered arsenomolybdate [Co(H 2 O) 6 ] K 2 [As 6 CoMo 6 O 30 ] was isolated by reaction of [Co(H 2 O) 6 ]Cl 2 , Na 3 [As 3 Mo 3 O 15 ]·10H 2 O, and KCl in aqueous solution at room temperature. Since then, some functionalized bis(As 3 O 3 )-capped M-centered (M = Co, Mo, Cu, Zn, and Ni) Anderson-type arsenomolybdate derivatives are consecutively reported. ,,, In comparison with the previously reported organic–inorganic hybrid bis(As 3 O 3 )-capped, Cu-centered Anderson-type arsenomolybdates (H 2 en)[Cu(en) 2 ][(Cu O 6 )Mo 6 O 18 (As 3 O 3 ) 2 ]·10H 2 O ( A ), [Cu(imi) 2 ] 2 [(CuO 6 )(As 3 O 3 ) 2 Mo 6 O 18 ] [Cu(imi) 2 ] 2 ( B ), and (C 5 H 5 NH) 2 (H 3 O) 2 [(CuO 6 )Mo 6 O 18 (As 3 O 3 ) 2 ] ( C ), their common characteristic is that they all were prepared under hydrothermal conditions by making use of the same copper source of CuCl 2 ·2H 2 O; however, four evident discrepancies between them are also observed. (a) Their arsenic and molybdenum sources are different: As 2 O 3 and (NH 4 ) 6 Mo 7 O 24 ·4H 2 O for 1 and A , NaAsO 2 and (NH 4 ) 6 Mo 7 O 24 ·4H 2 O for B , NaAsO 2 and Na 2 MoO 4 ·2H 2 O for C .…”