A new polymorph of 4′-tolyl-2,2′:6′,2′′-terpyridine (ttpy) and the single crystal structures of [Fe(ttpy)2][PF6]2 and [Ru(ttpy)2][PF6]2

Beves, Jonathon E.; Chwalisz, Paulina; Constable, Edwin C.; Housecroft, Catherine E.; Neuburger, Markus; Schaffner, Silvia; Zampese, Jennifer A.

doi:10.1016/j.inoche.2008.04.033

Cited by 27 publications

(3 citation statements)

References 33 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Fe(BF 4 ) 2 that was popularly employed to prepare homoleptic bis-ligand complexes such as [Fe(4 0 -tolyl-2,2 0 :6 0 ,2 00 -tpy) 2 ]$[2(BF 4 )]. 23 Thus, the reaction between L and Fe(BF 4 ) 2 $4H 2 O was conducted to give the homoleptic iron(II) complex (7) in a cyan colour, which reacted in situ with Co(SCN) 2 (2.0 equiv.) by the same layering method as for 1-4.…”

Section: Mononuclear Cu II and Zn Ii Complexesmentioning

confidence: 99%

“…All Fe-N bonds and N-Fe-N angles are in the regular range as found in the reported structures of the cations [Fe(4 0 -tolyl-2,2 0 :6 0 ,2 00 -tpy) 2 ] 2+ and [Fe(4 0 -pyridyl-2,2 0 :6 0 ,2 00 -tpy) 2 ] 2+ . 23 However, an important characteristic of 5 is that all four outer N-donors of [Fe(L) 2 ] 2+ still remain non-coordinated, although an excess amount of Co(SCN) 2 was used in the separate reaction. Instead, the Co II centre exists in the structure of 5 as a [Co(SCN) 4 ] 2À counterion through anion exchange with [BF 4 ] À .…”

Section: Mononuclear Cu II and Zn Ii Complexesmentioning

confidence: 99%

See 1 more Smart Citation

Assembling mono-, di- and tri-nuclear coordination complexes with a ditopic analogue of 2,2′:6′,2′′-terpyridine: syntheses, structures and catalytic studies

et al. 2015

View full text Add to dashboard Cite

ARTICLEThis journal is 4-Phenyl-2,6-bis(2'-pyrazinyl)pyridine (L) as a closely related ditopic analogue of 2,2':6',2''terpyridine, was synthesized through a facile one-pot Kröhnke condensation, along with the structural determination of transition metal coordination assemblies of this ditopic ligand. A variety of metal complexes including mono-, di-and tri-nuclear structures 1-6 were revealed, dependent upon the metal salts and reaction conditions employed. Although reactions of L with copper(II) or zinc(II) nitrates and zinc(II) iodide gave only simple mononuclear mono-ligand complexes, that using cobalt thiocyanate led to a dinuclear dimeric complex. The potential of outer N-donors of the ligand backbone in extending mononuclear complexes into polynuclear assemblies was further investigated. The solution reaction of [Fe(L)2] 2+ species with Co II gave an ionic complex containing [Co(SCN)4] 2counterions, leaving the outer pyrazinyl-N noncoordinated. However, the solvothermal assembly of L with copper(II) chloride facilitates the formation of a discrete trinuclear complex via outer-N coordination, indicating the promising applications of L in constructing complicated supramolecular structures. Catalytic tests were carried out on copper(II)-and cobalt(II)-containing complexes 1 and 4-6 for the aerobic alcohol oxidation. Up to 99% conversion of benzylic alcohol to benzaldehyde was observed when 1 (1 mol%) was used as a catalyst, in the presence of TEMPO (2,2,6,6-tetramethylpiperidinyl-1-oxyl) and DMAP (4-dimethylaminopyridine) in acetonitrile, while the trinuclear 6 was a better catalyst when the reaction was conducted in water.

show abstract

Section: Mononuclear Cu II and Zn Ii Complexesmentioning

confidence: 99%

Section: Mononuclear Cu II and Zn Ii Complexesmentioning

confidence: 99%

Assembling mono-, di- and tri-nuclear coordination complexes with a ditopic analogue of 2,2′:6′,2′′-terpyridine: syntheses, structures and catalytic studies

et al. 2015

View full text Add to dashboard Cite

show abstract

“…Acetonitrile (Rathburn, HPLC grade), tetra- n -butylammonium hexafluorophosphate (TBAPF 6 , Aldrich), and 4-bromobenzenediazonium tetrafluoroborate (ArN 2 + , BF 4 – , Accros) were used as received. Tri( p -bromophenyl)amine (tBrTPA) and iron(II) and ruthenium(II) bis(4′-(4-methylphenyl)-2,2′:6′,2″-terpyridine) hexafluorophosphate, respectively, denoted ( 1 ) and ( 2 ) were prepared according to the literature. Iron(II) and ruthenium(II) bis(4′-(4-(2-mercapto-ethoxy)phenyl)-2,2′:6′,2″-terpyridine) hexafluorophosphate ( 3 ) and ( 4 ) were synthesized following already reported procedures …”

Section: Methodsmentioning

confidence: 99%

Photoinduced Energy vs Electron Transfer Between Fe(II) and Ru(II) Bisterpyridyl Complexes in Solution and Grafted on a Gold Surface

et al. 2013

View full text Add to dashboard Cite

show abstract

Synthesis, Stability and Sensitised Lanthanide Luminescence of Heterobimetallic d/f Terpyridine Complexes

et al. 2014

View full text Add to dashboard Cite

The synthesis, solution behavior and photophysical properties of several heteronuclear bimetallic d/f complexes that utilise a Ru II bis-terpyridine moiety as the sensitiser for Eu III , Nd III and Yb III luminescence are reported and compared to a Gd III analogue. The former compounds display sensitised emission in the visible and near-infrared (NIR) regions depending on the choice of the Ln III cation. We illustrate that sensitised lanthanide emission can operate by two distinctly different pathways that involve either the triplet ligand-[a]

show abstract

A new polymorph of 4′-tolyl-2,2′:6′,2′′-terpyridine (ttpy) and the single crystal structures of [Fe(ttpy)2][PF6]2 and [Ru(ttpy)2][PF6]2

Cited by 27 publications

References 33 publications

Assembling mono-, di- and tri-nuclear coordination complexes with a ditopic analogue of 2,2′:6′,2′′-terpyridine: syntheses, structures and catalytic studies

Assembling mono-, di- and tri-nuclear coordination complexes with a ditopic analogue of 2,2′:6′,2′′-terpyridine: syntheses, structures and catalytic studies

Photoinduced Energy vs Electron Transfer Between Fe(II) and Ru(II) Bisterpyridyl Complexes in Solution and Grafted on a Gold Surface

Synthesis, Stability and Sensitised Lanthanide Luminescence of Heterobimetallic d/f Terpyridine Complexes

Contact Info

Product

Resources

About